相关实验视频
Updated: May 14, 2025

06:58
Zinc-Sponge Battery Electrodes that Suppress Dendrites
Published on: September 29, 2020
4.3K
在性电解质中的化物介导的Ag-Zn电池
Jiajie Shen1, Wenjiao Ma1, Jianhui Jin1
1State Key Laboratory of Chemo and Biosensing, Joint International Research Laboratory of Energy Electrochemistry, College of Chemistry and Chemical Engineering, Hunan University, Changsha 410082, China. xliang@hnu.edu.cn.
概括
将化物离子添加到性银电池中,通过减少降解并实现基于聚合物的稳定白银阴极,可以显著提高性能. 这一创新导致了高效且持久的可充电电池.
科学领域:
- 电化学 电化学 电化学
- 材料科学 材料科学 材料科学
- 储能 储能 储能 储能 储能 储能
背景情况:
- 性银电池遭受阴极溶解和穿效应,限制其周期寿命.
- 在循环过程中银色极体的体积变化会导致容量降低.
研究的目的:
- 为了提高性银电池的循环稳定性和性能.
- 为了减轻银电池系统中的关键降解机制.
主要方法:
- 加入化物离子 (Br-) 作为电解质添加剂.
- 设计一种基于聚合物的自支银色阴极.
- 电化学循环和性能评估.
主要成果:
- 化物离子有效地抑制了穿效应和阴极溶解.
- 基于聚合物的阴极适应了体积变化,最大限度地降低了降解.
- 该电池实现了超过370个循环,高达99.3%的库伦比效率和出色的容量保留.
- 证明了 2.3 mA h cm-2 的高面积容量.
结论:
- 化物介导的电解质添加剂和先进的阴极设计显著提高了银电池的性能.
- 开发的系统对实用,高性能可充电电池应用有很大的前景.
相关概念视频
Batteries and Fuel Cells
26.8K
A battery is a galvanic cell that is used as a source of electrical power for specific applications. Modern batteries exist in a multitude of forms to accommodate various applications, from tiny button batteries such as those that power wristwatches to the very large batteries used to supply backup energy to municipal power grids. Some batteries are designed for single-use applications and cannot be recharged (primary cells), while others are based on conveniently reversible cell reactions that...
26.8K
Standard Electrode Potentials
42.8K
On comparing the reactivity of silver and lead, it is observed that the two ionic species, Ag+ (aq) and Pb2+ (aq), show a difference in their redox reactivity towards copper: the silver ion undergoes spontaneous reduction, while the lead ion does not. This relative redox activity can be easily quantified in electrochemical cells by a property called cell potential. This property is commonly known as cell voltage in electrochemistry, and it is a measure of the energy which accompanies the charge...
42.8K
Voltaic/Galvanic Cells
55.2K
Spontaneous Chemical Reactions
Spontaneous redox reactions occur abundantly in nature. The chemical reaction occurring in a disposable AA battery powering our remote controls is one such example of a spontaneous redox reaction. Another example is the immersion of coiled copper wire into an aqueous silver nitrate solution. The reaction shows a gradual, visually impressive color change from colorless to bright blue and the formation of a grey precipitate on the copper wire. In this experiment,...
Spontaneous redox reactions occur abundantly in nature. The chemical reaction occurring in a disposable AA battery powering our remote controls is one such example of a spontaneous redox reaction. Another example is the immersion of coiled copper wire into an aqueous silver nitrate solution. The reaction shows a gradual, visually impressive color change from colorless to bright blue and the formation of a grey precipitate on the copper wire. In this experiment,...
55.2K
Electrophilic Addition to Alkynes: Hydrohalogenation
9.8K
Electrophilic addition of hydrogen halides, HX (X = Cl, Br or I) to alkenes forms alkyl halides as per Markovnikov's rule, where the hydrogen gets added to the less substituted carbon of the double bond. Hydrohalogenation of alkynes takes place in a similar manner, with the first addition of HX forming a vinyl halide and the second giving a geminal dihalide.
9.8K
Chemical Reactions in Aqueous Solutions
59.4K
Chemical substances interact in many different ways. Certain chemical reactions exhibit common patterns of reactivity. Due to the vast number of chemical reactions, it becomes necessary to classify them based on the observed patterns of interaction.
59.4K
Acid Halides to Alcohols: LiAlH4 Reduction
2.6K
Acid halides are reduced to alcohols in the presence of a strong reducing agent like lithium aluminum hydride.
The mechanism proceeds in three steps. First, the nucleophilic hydride ion attacks the carbonyl carbon of the acid halide to form a tetrahedral intermediate. Next, the carbonyl group is re-formed, and the halide ion departs as a leaving group, generating an aldehyde. A second nucleophilic attack by the hydride yields an alkoxide ion, which, upon protonation, gives a primary alcohol as...
The mechanism proceeds in three steps. First, the nucleophilic hydride ion attacks the carbonyl carbon of the acid halide to form a tetrahedral intermediate. Next, the carbonyl group is re-formed, and the halide ion departs as a leaving group, generating an aldehyde. A second nucleophilic attack by the hydride yields an alkoxide ion, which, upon protonation, gives a primary alcohol as...
2.6K

