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稀土单原子混合眼镜用于近红外II光学波导
Meiqi Dai1, Bo Zhou1, Dongpeng Yan1
1Key Laboratory of Radiopharmaceuticals, Ministry of Education, College of Chemistry, Beijing Normal University, Beijing, 100875, P.R. China.
Angewandte Chemie (International ed. in English)
|April 23, 2025
概括
新的稀土混合眼镜提供高效的近红外II (NIR-II) 辐射和超低损失光学波导. 这些材料利用Nd3+合复杂玻璃,用于通信和存储的先进光子应用.
科学领域:
- 材料科学 材料科学 材料科学
- 光子学 是一个光子学.
- 化学 化学 化学
背景情况:
- 现代信息技术需要先进的光学波导来进行通信和存储.
- 实现高效的近红外 (NIR) 发射与最小的光学损失是一个重大挑战.
研究的目的:
- 开发用于高效的NIR-II发射和超低损耗光学波导的新材料.
- 解决当前稀土基材料在光子应用中的局限性.
主要方法:
- 通过自下自上自组装合成稀土单原子混合玻璃.
- 使用 Nd3+ 合复杂玻璃的超长光.
- 用于光学波导的1D和2D玻璃微结构的制造.
主要成果:
- 实现了高达1.32微米的NIR-II发射记录,光发光量子收益率 (PLQY) 为~5.7%.
- 证明了Nd3+离子的高效敏感化,其光能转移效率为93.55%.
- 获得的超低光学损失系数为0.978 dB mm-1 (819 nm) 和5.1 dB mm-1 (1048 nm) 在杂微观结构中.
结论:
- 具有超长光的金属有机复合玻璃作为有效的敏化矩阵来增强NIR-II发射.
- 开发的混合眼镜可以用超低损失光学波导制造1D和2D微结构.
- 这些材料对信息通信和存储中的先进NIR-II光子应用具有前景.
相关概念视频
IR Absorption Frequency: Hybridization
Hydrocarbons such as alkanes, alkenes, and alkynes show characteristic C–H stretching absorption bands. These IR stretching frequencies depend on the hybridization of the involved carbon atom and can be explained in terms of the s character of each hybridized atomic orbital.
Among the sp, sp2, and sp3 hybridized orbitals, sp orbitals have the maximum s character (50%). Consequently, the electrons are held more closely to the nucleus, resulting in stronger and shorter C–H bonds that stretch at a...
Among the sp, sp2, and sp3 hybridized orbitals, sp orbitals have the maximum s character (50%). Consequently, the electrons are held more closely to the nucleus, resulting in stronger and shorter C–H bonds that stretch at a...
IR Absorption Frequency: Delocalization
Electron delocalization refers to the distribution of electrons across multiple atoms within a molecule rather than being confined to a single atom or bond. This phenomenon is common in systems with conjugated bonds—structures where alternating single and double bonds allow π-electrons to move freely across the network. The movement of electrons stabilizes the molecule and can affect various chemical properties, including vibrational frequencies observed in IR spectroscopy.
In IR spectroscopy,...
In IR spectroscopy,...

