晶化阶段调节BaO-CaO-SiO2玻璃陶具有高热膨胀系数的玻璃陶
Haonan Hu1,2, Yongyuan Liang3, Qifan Guan1,4
1CAS Key Laboratory of Inorganic Functional Materials and Devices, Shanghai Institute of Ceramics, Chinese Academy of Sciences, Shanghai 201899, China.
Materials (Basel, Switzerland)
|April 24, 2025
概括
在BaO-CaO-SiO2玻璃中改变Ba/Ca比率会改变网络连接和结晶. 添加石英 (α-SiO2) 优化了先进电子包装基板的相位.
科学领域:
- 材料科学 材料科学 材料科学
- 玻璃科学 玻璃科学
- 陶工程 陶工程 陶工程
背景情况:
- 酸 (BCS) 玻璃正在探索电子应用.
- 了解构成对玻璃结构和性能的影响至关重要.
研究的目的:
- 研究Ba/Ca比对BCS玻璃结构,结晶和热膨胀的影响.
- 评估α-SiO2 (石英) 在为电子基板量身定制BCS玻璃陶中的作用.
主要方法:
- 在BCS玻璃组成中Ba/Ca比率的系统变化.
- 使用Qn单位表征分析玻璃网络结构.
- 在烧结玻璃陶中进行相位识别和量化.
- 测量热物理和介电性质.
主要成果:
- 增加Ba/Ca比率减少了玻璃网络连接 (Q4到Q3单位).
- 在Tc.以上的烧结时,Ba/Ca比率会影响结晶阶段.
- 添加15%的α-SiO2促进了BaSi2O5阶段的形成.
- 优化α-SiO2修改的BCS玻璃陶显示低CTE (12.10ppm/°C) 和良好的介电性质 (εr=7.49,tanδ=4.96×10−4,Q×f=27,034 GHz).
结论:
- Ba/Ca比率和α-SiO2含量是控制BCS玻璃陶性能的关键因素.
- 用α-SiO2优化的BCS玻璃陶适用于射频模块和电子包装.
- 这项研究提供了对先进陶材料结构性质关系的见解.
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