关于溶解有机物在电动力学硫酸盐处理后的分子洞察力:异原子诱导的抗性
Xinxu Niu1, Jian Liu2, Shaohua Chen3
1State Key Laboratory for Advanced Environmental Technology, Institute of Urban Environment, Chinese Academy of Sciences, Xiamen 361021, China; College of Environment & Safety Engineering, Fuzhou University, Fuzhou 350108, China.
电动力学硫酸盐处理氧化沉积物中的溶解有机物 (DOM). 这个过程改变了DOM,产生了更耐药的氧化分子,影响了修复评估.
科学领域:
- 环境科学 环境科学
- 环境化学环境化学
- 整治技术 整治技术
背景情况:
- 电动力学增强的 in situ 化学氧化是一种有前途的沉积物修复技术.
- 在这个过程中,溶解有机物 (DOM) 的分子变化尚未得到充分理解.
研究的目的:
- 为了研究DOM在电动力学 (EK) 硫酸盐处理过程中的分子转化.
- 在DOM中识别关键的分子变化和反应途径.
主要方法:
- 在EK-硫酸盐处理前后对DOM分子特征的分析.
- 分子组成,氧化状态和异原子含量变化的表征.
主要成果:
- DOM从减少状态转变为氧化状态,低O/C分子减少,高O/C分子增加.
- 含有异原子的分子,特别是含有N和Cl的分子,以耐药分数积累.
- 氧添加和脱基化被确定为主要的转化途径.
结论:
- EK-硫酸盐处理显著改变DOM分子结构,增加其氧化和抗性.
- 了解这些DOM转换对于评估这种修复技术的长期有效性和潜在风险至关重要.
更多相关视频
09:00Electrochemical Detection of Deuterium Kinetic Isotope Effect on Extracellular Electron Transport in Shewanella oneidensis MR-1
Published on: April 16, 2018
07:44Determining the Chemical Composition of Corrosion Inhibitor/Metal Interfaces with XPS: Minimizing Post Immersion Oxidation
Published on: March 15, 2017
相关概念视频
Extraction: Advanced Methods
Precipitation and Co-precipitation
Electrophilic Aromatic Substitution: Sulfonation of Benzene
Solubility
A solution is a homogeneous mixture composed of a solvent, the major component, and a solute, the minor component. The physical state of a solution—solid, liquid, or gas—is typically the same as that of the solvent. Solute concentrations are often described with qualitative terms such as dilute (of relatively low concentration) and concentrated (of relatively high concentration).
In a solution, the solute particles (molecules,...
π Electron Effects on Chemical Shift: Overview
Sample Preparation for Analysis: Advanced Techniques
Acid digestion with strong acids is commonly used to dissolve inorganic materials that are insoluble (do not dissolve) in water. This method can be useful for...
