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Updated: May 20, 2025

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不对称地定制的催化剂用于用非贵重材料进行电化学能量转换

Lei Zhang1, Qiaoling Xu1, Lu Xia2

  • 1School of Materials Science and Engineering, Anhui Province Key Laboratory of Specialty Polymers, Anhui University of Science and Technology, Huainan, Anhui 232001, P. R. China.

Chemical Society reviews
|April 25, 2025
PubMed
概括

不对称的电催化剂 (ATE) 为储能和化学转化提供了可持续的解决方案,克服了传统贵金属催化剂的局限性. 这些先进的材料利用非贵金属过渡金属催化剂,增强水电解和金属空气电池中的活性和稳定性.

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Catalytic hydrogenation of alkenes is a transition-metal catalyzed reduction of the double bond using molecular hydrogen to give alkanes. The mode of hydrogen addition follows syn stereochemistry.
The metal catalyst used can be either heterogeneous or homogeneous. When hydrogenation of an alkene generates a chiral center, a pair of enantiomeric products is expected to form. However, an enantiomeric excess of one of the products can be facilitated using an enantioselective reaction or an...
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