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相关概念视频

Molecular and Ionic Solids02:54

Molecular and Ionic Solids

16.5K
Crystalline solids are divided into four types: molecular, ionic, metallic, and covalent network based on the type of constituent units and their interparticle interactions.
Molecular Solids
Molecular crystalline solids, such as ice, sucrose (table sugar), and iodine, are solids that are composed of neutral molecules as their constituent units. These molecules are held together by weak intermolecular forces such as London dispersion forces, dipole-dipole interactions, or hydrogen bonds, which...
16.5K
Ionic Crystal Structures02:42

Ionic Crystal Structures

13.9K
Ionic crystals consist of two or more different kinds of ions that usually have different sizes. The packing of these ions into a crystal structure is more complex than the packing of metal atoms that are the same size.
Most monatomic ions behave as charged spheres, and their attraction for ions of opposite charge is the same in every direction. Consequently, stable structures for ionic compounds result (1) when ions of one charge are surrounded by as many ions as possible of the opposite...
13.9K
Trends in Lattice Energy: Ion Size and Charge02:54

Trends in Lattice Energy: Ion Size and Charge

23.5K
An ionic compound is stable because of the electrostatic attraction between its positive and negative ions. The lattice energy of a compound is a measure of the strength of this attraction. The lattice energy (ΔHlattice) of an ionic compound is defined as the energy required to separate one mole of the solid into its component gaseous ions. For the ionic solid sodium chloride, the lattice energy is the enthalpy change of the process:
23.5K
Facilitated Transport01:19

Facilitated Transport

10.6K
The chemical and physical properties of plasma membranes cause them to be selectively permeable. Since plasma membranes have both hydrophobic and hydrophilic regions, substances need to be able to transverse both regions. The hydrophobic area of membranes repels substances such as charged ions. Therefore, such substances need special membrane proteins to cross a membrane successfully. In  facilitated transport, also known as facilitated diffusion, molecules and ions travel across a...
10.6K
Crystal Field Theory - Octahedral Complexes02:58

Crystal Field Theory - Octahedral Complexes

25.7K
Crystal Field Theory
To explain the observed behavior of transition metal complexes (such as colors), a model involving electrostatic interactions between the electrons from the ligands and the electrons in the unhybridized d orbitals of the central metal atom has been developed. This electrostatic model is crystal field theory (CFT). It helps to understand, interpret, and predict the colors, magnetic behavior, and some structures of coordination compounds of transition metals.
CFT focuses on...
25.7K
Formation of Complex Ions03:45

Formation of Complex Ions

23.0K
A type of Lewis acid-base chemistry involves the formation of a complex ion (or a coordination complex) comprising a central atom, typically a transition metal cation, surrounded by ions or molecules called ligands. These ligands can be neutral molecules like H2O or NH3, or ions such as CN− or OH−. Often, the ligands act as Lewis bases, donating a pair of electrons to the central atom. These types of Lewis acid-base reactions are examples of a broad subdiscipline called coordination...
23.0K

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相关实验视频

Updated: May 8, 2025

Electric-field Control of Electronic States in WS2 Nanodevices by Electrolyte Gating
10:36

Electric-field Control of Electronic States in WS2 Nanodevices by Electrolyte Gating

Published on: April 12, 2018

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在超离子晶体中运输能量.

Wenxiang Liu1, Yanguang Zhou1

  • 1The Hong Kong University of Science and Technology, Department of Mechanical and Aerospace Engineering, Clear Water Bay, Kowloon, Hong Kong SAR.

Physical review letters
|April 25, 2025
PubMed
概括

超离子晶体通过原子振动和离子扩散传递热量. 它们复杂的导热能力受到这些通路的影响,解释了实验观察到的各种温度依赖性.

科学领域:

  • 凝聚物质物理学 凝聚物质物理学
  • 材料科学 材料科学 材料科学
  • 热力学是一种热力学.

背景情况:

  • 超离子晶体表现出复杂的热传输特性.
  • 了解这些材料的导热度和温度依赖性至关重要.

研究的目的:

  • 提出一个严格的概念来描述超离子晶体中的热传输.
  • 阐明它们多样化的导热行为背后的机制.

主要方法:

  • 应用奥纳塞格反向定理的应用.
  • 通过原子振动,散和热扩散合进行热能转移的分析.

主要成果:

  • 来自原子振动的导热性随着温度的增加而降低.
  • 由于增强的离子流动性,来自散的热导率随着温度的增加而增加.
  • 热扩散合的导热率是可以忽略不计的.

结论:

  • 表面的导热率是由振动导电和散力扩散之间的相互作用决定的.
  • 该模型解释了在超离子晶体中热导率的观察到的负,弱和正温度依赖性.

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