在扭曲石墨中超接口的超高热导电性
Fuwei Yang1,2,3,4, Wenjiang Zhou1,5,6, Zhibin Zhang7
1Peking University, National Key Laboratory of Advanced MicroNanoManufacture Technology, Beijing 100871, China.
Physical review letters
|April 25, 2025
概括
范德瓦尔斯材料中层间旋转使结构超性成为可能,并控制热流. 这项研究精确地测量了扭曲石墨的导热率,揭示了显著的差异和滑动阻力和热传输之间的联系.
科学领域:
- 材料科学 材料科学 材料科学
- 凝聚物质物理学 凝聚物质物理学
- 纳米技术纳米技术
背景情况:
- 范德瓦尔斯 (vdW) 材料在间层旋转时表现出独特的特性,包括结构超性和热管理潜力.
- 控制扭曲的vdW材料中的热流是理论上预测的,但由于结果不一致,在实验上具有挑战性.
研究的目的:
- 实验测量和描述VDW材料中内在扭曲接口的热传输特性.
- 为了研究层间旋转,滑动阻力和导热率之间的相关性.
- 为了在先进的电子产品中为支持扭转的热管理奠定基础.
主要方法:
- 具有扭曲接口的微型制造石墨板的同时机械表征和热量测量.
- 原子模拟以阐明声子在界面热传输中的作用.
主要成果:
- 超滑接口实现了约600MWm-2K-1的热导率,明显高于人工vdW结构.
- 在旋转接口到锁定状态时,观察到热导电率>30倍的变化.
- 原子模拟确定了横向声学声子在界面热传输中占主导地位.
结论:
- 在扭曲的vdW材料中,界面热传输和滑动阻力之间存在直接的相关性.
- 扭转启用热管理是一种可行的策略,特别有利于twistronics和slidetronics应用.
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