聚乙烯非线性弹性模块的温度依赖性
Andrey V Belashov1, Anna A Zhikhoreva1, Yaroslav M Beltukov1
1Ioffe Institute, Russian Academy of Sciences, 26, Polytekhnicheskaya, 194021 St. Petersburg, Russia.
Polymers
|April 26, 2025
概括
聚合物的非线性弹性模块表现出显著的温度依赖性,特别影响了l和m模块. 这种行为与高温时的频率变化有关,影响动态负载预测.
科学领域:
- 材料科学 材料科学 材料科学
- 聚合物物理 聚合物物理
- 声学 声学 在声学方面
背景情况:
- 聚合物的非线性弹性特性对于预测对动态负荷的反应至关重要.
- 了解这些非线性模块的温度敏感性至关重要,但人们对其了解甚少.
- 之前的研究表明,聚钢的非线性弹性模块存在频率依赖.
研究的目的:
- 为了研究聚烯中非线性弹性 (Murnaghan) 模块的温度依赖性.
- 量化各种非线性模块 (l,m,n) 的温度敏感性.
- 为了将温度效应与频率依赖性相关联.
主要方法:
- 用声弹性效应进行测量.
- 分析了纵向和剪切超声波速度的压力依赖.
- 在25-65°C的温度范围内进行测量,频率为0.7-3MHz.
主要成果:
- 发现非线性模块l和m的温度易感性比线性模块λ和μ的温度易感性大两倍.
- 温度对n模块的变化是最小的,并且在测量容忍范围内.
- 观察到的趋势表明,随着温度的增加,非线性模块会转移到更高的频率.
结论:
- 聚合物在其非线性弹性特性中表现出显著的温度敏感性,特别是l和m Murnaghan模块.
- 这种温度依赖与频率变化密切相关,影响动态条件下的材料行为.
- 这些发现为在不同热环境下准确建模聚合物复合材料提供了关键数据.
相关概念视频
Strain and Elastic Modulus
3.4K
The quantity that describes the deformation of a body under stress is known as strain. Strain is given as a fractional change in either length, volume, or geometry under tensile, volume (also known as bulk), or shear stress, respectively, and is a dimensionless quantity. The strain experienced by a body under tensile or compressive stress is called tensile or compressive strain, respectively. In contrast, the strain experienced under bulk stress and shear stress is known as volume and shear...
3.4K
Relation between Poisson's ratio, Modulus of Elasticity and Modulus of Rigidity
223
Deformation occurs in axial and transverse directions when an axial load is applied to a slender bar. This deformation impacts the cubic element within the bar, transforming it into either a rectangular parallelepiped or a rhombus, contingent on its orientation. This transformation process induces shearing strain. Axial loading elicits both shearing and normal strains. Applying an axial load instigates equal normal and shearing stresses on elements oriented at a 45° angle to the load axis.
223
Molecular Weight of Step-Growth Polymers
2.1K
Step growth polymerization involves bi or multifunctional monomers. Bifunctional monomers react to form linear step growth polymers, whereas multifunctional monomers react to form non-linear or branched polymers.
As the step-growth polymerization involves step-wise condensation of monomers, the molecular weight also builds up eventually. Consequently, high molecular weight polymers are obtained at the late stages of the polymerization, where 99% of monomers have been consumed.
The extent of the...
As the step-growth polymerization involves step-wise condensation of monomers, the molecular weight also builds up eventually. Consequently, high molecular weight polymers are obtained at the late stages of the polymerization, where 99% of monomers have been consumed.
The extent of the...
2.1K
Elasticity in Concrete
72
Upon subjecting concrete to moderate or high uniaxial compressive or tensile stresses, the strain response is non-linear relative to the stress applied. As the stress is removed, the resulting stress-strain curve deviates from the original path traced during loading, creating a hysteresis loop, indicative of the concrete's non-linear and non-elastic properties. Typically, a material's modulus of elasticity, which is a measure of the material's stiffness, is inferred from the linear...
72
Polymer Classification: Architecture
2.6K
Polymers are classified as linear or branched on the basis of their chain architecture. The polymer chains in linear polymers have a long chain-like structure with minimal to no branching at all. Even if a polymer features large substituent groups on the monomer, which appear as branches to the skeleton, it is not considered a branched polymer. A branched polymer contains secondary polymer chains that arise from the main polymer chain. The branching occurs when the polymer growth shifts from...
2.6K
Temperature Dependent Deformation
123
In a nonhomogeneous rod made up of steel and brass, restrained at both ends and subjected to a temperature change, several steps are involved in calculating the stress and compressive load. Due to the problem's static indeterminacy, one end support is disconnected, allowing the rod to experience the temperature change freely. Next, an unknown force is applied at the free end, triggering deformations in the rod's steel and brass portions. These deformations are then calculated and added...
123


