动态诱导基于转换的极退化通过价值状态和机械裂
Shuaitong Liang1, Shuoshuo Liu1, Junping Miao1
1International Joint Laboratory of New Textile Materials and Textiles of Henan Province, Zhongyuan University of Technology, Zhengzhou, 450007, China.
Small (Weinheim an der Bergstrasse, Germany)
|April 26, 2025
概括
在离子电池循环过程中,电极颗粒故障是由裂和空隙形成引起的. 维度工程可以减轻这种情况,提高电池的稳定性和容量.
科学领域:
- 材料科学 材料科学 材料科学
- 电化学 电化学 电化学
- 纳米技术 纳米技术
背景情况:
- 电化学储能性能受到晶体电极材料中的离子大小的限制.
- 了解电极材料的动态变化对于开发先进电池至关重要.
研究的目的:
- 为了研究化/脱化过程中球形NiS2活性颗粒的物理化学变化.
- 为了确定离子电池中电极颗粒故障的根本原因.
主要方法:
- 使用基于同步的传输X射线显微镜.
- 采用近边光谱的X射线吸收来分析NiS2粒子的微区域.
主要成果:
- 在NiS2粒子中观察到裂和空隙形成,随着度的增加.
- 确定了金属元素在内部和外部粒子区域之间的价值状态的显著差异.
- 确定空隙诱导的裂纹是电极粒子故障的主要原因.
结论:
- 离子电池中的电极颗粒故障与空隙形成和裂传播有关.
- 维度工程策略可以减轻故障,提高电池性能.
- 这些发现为开发高容量,稳定的离子电池铺平了道路.
更多相关视频
10:41The Effect of Charging and Discharging Lithium Iron Phosphate-graphite Cells at Different Temperatures on Degradation
Published on: July 18, 2018
15.4K
12:18Co-localizing Kelvin Probe Force Microscopy with Other Microscopies and Spectroscopies: Selected Applications in Corrosion Characterization of Alloys
Published on: June 27, 2022
2.5K
相关概念视频
Microcracking in Concrete
87
Microcracking in concrete refers to the tiny cracks that can form within the material even before any external load is applied. These microcracks typically occur at the interface between the coarse aggregate and the hydrated cement paste, often as a result of differential volume changes prompted by variations in stress-strain behavior, as well as thermal and moisture movement. Initially, these microcracks remain stable and do not grow substantially until the concrete is stressed to about 30...
87
Corrosion of Reinforcement
119
The corrosion of steel reinforcement within concrete is a process influenced by the material's inherent properties and external factors. The high pH level of around 13, provided by calcium hydroxide present in concrete, initially protects the steel reinforcement by promoting the formation of a passive iron oxide layer on its surface.
However, over time and under certain conditions like carbonation, chloride ingress, and cracking this protective state can be compromised. Steel has areas with...
However, over time and under certain conditions like carbonation, chloride ingress, and cracking this protective state can be compromised. Steel has areas with...
119
Corrosion
23.5K
The degradation of metals due to natural electrochemical processes is known as corrosion. Rust formation on iron, tarnishing of silver, and the blue-green patina that develops on copper are examples of corrosion. Corrosion involves the oxidation of metals. Sometimes it is protective, such as the oxidation of copper or aluminum, wherein a protective layer of metal oxide or its derivatives forms on the surface, protecting the underlying metal from further oxidation. In other cases, corrosion is...
23.5K
Van de Graaff Generator
1.6K
Van de Graaff generators (or Van de Graaffs) are devices used to demonstrate high voltage due to static electricity that can also be used for research. Robert Van de Graaff first built one in 1931 (based on original suggestions by Lord Kelvin) for use in nuclear physics research.
Van de Graaff uses both smooth and pointed surfaces, conductors, and insulators to generate large static charges and, hence, large voltages. A substantial excess charge can be deposited on the sphere because it moves...
Van de Graaff uses both smooth and pointed surfaces, conductors, and insulators to generate large static charges and, hence, large voltages. A substantial excess charge can be deposited on the sphere because it moves...
1.6K
