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相关概念视频

Batteries and Fuel Cells03:12

Batteries and Fuel Cells

26.7K
A battery is a galvanic cell that is used as a source of electrical power for specific applications. Modern batteries exist in a multitude of forms to accommodate various applications, from tiny button batteries such as those that power wristwatches to the very large batteries used to supply backup energy to municipal power grids. Some batteries are designed for single-use applications and cannot be recharged (primary cells), while others are based on conveniently reversible cell reactions that...
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Electrolysis03:00

Electrolysis

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In a galvanic cell, the electrical work is done by a redox system on its surroundings as electrons produced by the spontaneous redox reactions are transferred through an external circuit. Alternatively, an external circuit does work on a redox system by imposing a voltage sufficient to drive an otherwise nonspontaneous reaction in a process known as electrolysis. For instance, recharging a battery involves the use of an external power source to drive the spontaneous (discharge) cell reaction in...
25.7K
Electromotive Force02:36

Electromotive Force

25.5K
Electricity is generated by either electrons or ions flowing through a solution or a conducting medium. This flow of electrons or specifically electrical charge is defined as an electric current. When electrons move through a wire, they generate an electric current. It can be recalled  that in a redox reaction, electrons are lost and gained. In the spontaneous redox reaction of zinc  with copper, when zinc is immersed in a copper ion solution, a transfer of electrons from one...
25.5K
Arrhenius Plots02:34

Arrhenius Plots

37.5K
The Arrhenius equation relates the activation energy and the rate constant, k, for chemical reactions. In the Arrhenius equation, k = Ae−Ea/RT, R is the ideal gas constant, which has a value of 8.314 J/mol·K, T is the temperature on the kelvin scale, Ea is the activation energy in J/mole, e is the constant 2.7183, and A is a constant called the frequency factor, which is related to the frequency of collisions and the orientation of the reacting molecules.
The Arrhenius equation can...
37.5K
Standard Electrode Potentials03:02

Standard Electrode Potentials

42.7K
On comparing the reactivity of silver and lead, it is observed that the two ionic species, Ag+ (aq) and Pb2+ (aq), show a difference in their redox reactivity towards copper: the silver ion undergoes spontaneous reduction, while the lead ion does not. This relative redox activity can be easily quantified in electrochemical cells by a property called cell potential. This property is commonly known as cell voltage in electrochemistry, and it is a measure of the energy which accompanies the charge...
42.7K
ATP Driven Pumps I: An Overview01:27

ATP Driven Pumps I: An Overview

7.7K
ATP-driven pumps, also known as transport ATPases, are integral membrane proteins. They have binding sites for ATP located on the membrane's cytosolic side and the ion-conducting domain in the transmembrane region. These pumps use the free energy released from ATP hydrolysis to move the solutes across cell membranes against an electrochemical gradient.
There are four main types of ATP-driven pumps - P-type, V-type, F-type, and ABC transporter. All these pumps are of varying complexities and...
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相关实验视频

Updated: May 10, 2025

Probing and Mapping Electrode Surfaces in Solid Oxide Fuel Cells
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对半实证质子交换膜燃料电池模型不同激活过电压描述的比较.

Leonardo Fortuna Carneiro1, Nicolas Tadeu Domingues Fernandes2, Esly Ferreira da Costa Junior1,3

  • 1Postgraduate Program in Chemical Engineering, PPGEQ-UFMG, Federal University of Minas Gerais, Presidente Antônio Carlos Avenue, 6627, Pampulha, Belo Horizonte, Minas Gerais 31270-901, Brazil.

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PubMed
概括

这项研究比较了两个质子交换膜燃料电池模型. 聚合物模型为燃料电池性能提供了更好的准确性和物理解释,特别是在有限的数据的情况下.

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A Guide to Concentration Alternating Frequency Response Analysis of Fuel Cells
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On the Preparation and Testing of Fuel Cell Catalysts Using the Thin Film Rotating Disk Electrode Method
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On the Preparation and Testing of Fuel Cell Catalysts Using the Thin Film Rotating Disk Electrode Method

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相关实验视频

Last Updated: May 10, 2025

Probing and Mapping Electrode Surfaces in Solid Oxide Fuel Cells
15:08

Probing and Mapping Electrode Surfaces in Solid Oxide Fuel Cells

Published on: September 20, 2012

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A Guide to Concentration Alternating Frequency Response Analysis of Fuel Cells
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On the Preparation and Testing of Fuel Cell Catalysts Using the Thin Film Rotating Disk Electrode Method
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科学领域:

  • 电化学 电化学 电化学
  • 能源转换 能源转换
  • 材料科学 材料科学 材料科学

背景情况:

  • 质子交换膜燃料电池 (PEMFCs) 需要准确和简单的模型来预测性能.
  • 半经验模型被广泛使用,但可能缺乏详细的物理见解.
  • 参数估计对于完善燃料电池模型准确性至关重要.

研究的目的:

  • 使用参数估计,将标准半实证模型与PEMFC聚合模型进行比较.
  • 评估每个模型的物理解释性和适配精度.
  • 评估模型在表示像反应剂耗尽这样的现象方面的稳定性.

主要方法:

  • 在参数估计中使用非线性回归.
  • 用一个并行遗传算法来解决优化问题.
  • 用实验极化数据来适应和验证模型.

主要成果:

  • 与常见的半经验模型相比,聚合物模型证明了对实验极化数据的优越匹配.
  • 来自聚合物模型的参数提供了更直接的物理解释.
  • 聚合物模型在模拟高电流密度的反应物耗尽效应方面表现出更大的稳定性.

结论:

  • 聚合物模型与参数估计相结合,是开发准确的PEMFC模型的高效策略.
  • 这种方法在处理有限的实验数据时尤为有益.
  • 增强的物理解释性和稳定性使聚合物模型成为燃料电池研究的推工具.