隔离性聚烯 (iPP) 薄膜 - - 核心和外结晶度与通过纳米缩获得的机械性质的相关性
Miroslav Huskić1,2,3, Lidija Slemenik Perše4, Boris Orel5
1Faculty of Polymer Technology, Ozare 19, 2380 Slovenj Gradec, Slovenia.
Polymers
|April 28, 2025
概括
处理条件,如拉出速度和添加剂,显著影响同位性聚烯 (iPP) 薄膜的性能. 较高的速度和回收含量增加了iPP薄膜的晶度,硬度和弹性模量.
科学领域:
- 材料科学 材料科学 材料科学
- 聚合物科学 聚合物科学
- 机械工程 机械工程
背景情况:
- 化异性聚烯 (iPP) 薄膜被广泛用于包装.
- 了解结构-属性关系对于优化片性能至关重要.
研究的目的:
- 调查iPP薄膜晶度和机械性能之间的相关性.
- 为了确定拉出速度和添加剂类型对iPP薄膜特性的影响.
主要方法:
- 工业规模的iPP薄膜生产,含有不同的回收材料和添加剂.
- 闪光差分扫描热度计 (Flash DSC) 用于测量晶度.
- 纳米沉积试验用于评估硬度和弹性模量.
- 极化光学显微镜 (POM) 用于形态分析.
主要成果:
- 观察到一个皮肤核心结构,在内部表面具有更高的结晶度.
- 增加的拉出速度 (10 m/min) 导致更高的晶度,弹性模量和硬度.
- 回收PP和PP随机共聚物等添加剂影响了晶体结构和机械性能.
- POM证实了面向的皮肤层和分层的晶体结构.
结论:
- 加工条件,特别是拉出速度,显著影响iPP薄膜的机械性能.
- 添加回收聚烯或随机共聚合物会改变材料的晶体形态和性能.
- 优化生产参数是提高聚烯包装薄膜性能的关键.
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