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Updated: May 12, 2025

Preparation of Contiguous Bisaziridines for Regioselective Ring-Opening Reactions
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易于NN的Cis-Azobenzene与Bis-silylenes的纽带裂解

Yun Xiong1, Shenglai Yao1, Matthias Driess1

  • 1Department of Chemistry: Metalorganics and Inorganic Materials, Technische Universität Berlin, Strasse des 17. Juni 115, Sekr. C2, 10623, Berlin, Germany.

Angewandte Chemie (International ed. in English)
|April 28, 2025
PubMed
概括

这项研究揭示了合作性disilicon(II) bis-silylenes如何选择性地激活亚博烯异构体中的NN键. 不同的双烯结构导致不同的反应途径和产品,包括新的NN键裂解化合物.

关键词:
亚二二烯是一种亚二烯.合作性 合作性 合作性循环添加 循环添加酸盐激活激活方式锡利烯是一种基.

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