使用一个数值模型来评估SO2的吸收效率,通过硫酸在包装和喷雾列中的硫酸
Rodolphe Vautherin1,2, Hélène Métivier1, Anne Reguer2
1INSA Lyon, DEEP, UR7429, Villeurbanne 69621, France.
概括
这项研究比较了封装和喷雾柱的二氧化硫 (SO2) 吸收,发现封装柱更有效. 最佳条件包括控制缩二硫酸盐溶液和清洁气体的温度和S(IV) 度.
科学领域:
- 化学工程是化学工程的重要组成部分.
- 环境工程 环境工程
- 过程模拟过程模拟
背景情况:
- 消除二氧化硫 (SO2) 对环境保护至关重要.
- 对 SO2 吸收的包装和喷雾柱的比较研究是有限的.
- 数字建模提供了一种分析吸收柱中的气液转移的方法.
研究的目的:
- 以数值建模和比较 SO2 吸收效率在包装和喷雾柱.
- 为了研究运行参数 (L/G比,温度,S(IV) 度) 对SO2吸收的影响.
- 通过对工业试点工厂数据验证数值模型.
主要方法:
- 开发和应用一个数值模型,用于包装和喷雾柱.
- 在各种条件下模拟硫酸对SO2的吸收.
- 使用来自工业试点工厂的实验数据验证模型预测.
主要成果:
- 打包列显示出比喷雾列更高的SO2吸收效率.
- 包装列中的L/G比率降低表明能源成本较低.
- 吸收效率随着温度的提高而显著下降 (大约. 40%从40°C下降到70°C) 的情况.
- 液相中较高的S (IV) 度降低了SO2吸收效率.
结论:
- 与喷雾柱相比,包装柱在SO2吸收方面更有效.
- 温度和S(IV) 度是影响吸收效率的关键参数.
- 建议采用双列系统 (酸性pH用于度,基本性pH用于净化) 以实现最佳的SO2管理.
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