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Updated: May 15, 2025

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Research and Development of High-performance Explosives
Published on: February 20, 2016
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爆炸物的床和气壁速度:分析估计和热化学模拟
1CEA, DAM, Le Ripault, 37260 Monts, France. didier.mathieu@cea.fr.
Physical chemistry chemical physics : PCCP
|May 2, 2025
概括
对于有机爆炸物,Cγ方法准确地预测了Gurney速度,但对于含有金属的爆炸物,它很难. 对于气壁速度,热化学模拟提供了最好的准确性.
科学领域:
- 能量材料科学 能量材料科学
- 计算化学的计算化学
- 化学工程是化学工程的重要组成部分.
背景情况:
- Cγ方法是一种半经验分析模型,用于计算高能材料中的Gurney速度 (uG) 和气壁速度 (vs).
- 这个模型最初是为CHNO高爆炸物开发的,并已扩展到包括其他元素和低密度爆炸物.
研究的目的:
- 评估和扩大Cγ方法用于预测材料能量性能的适用性.
- 将Cγ方法的预测与热化学模拟结果进行比较.
- 评估Cγ方法对于设计新能源材料的适用性.
主要方法:
- 使用半实证Cγ方法计算格尼速度 (uG) 和气壁速度 (vs).
- 扩展了Cγ模型,以适应在低载荷密度下额外的元素和爆炸物.
- 将Cγ结果与从热化学模拟中获得的结果进行比较,并对vs.新引入的经验方程进行比较.
主要成果:
- 通过Cγ方法和热化学模拟,GG在有机高爆炸性物质中表现相似. 相对误差为 ~2.6%).
- 对于含有粉的爆炸物 - - 三醇,Cγ低估了GU.
- 对比的新实证方程表现优于格尼模型,但不如热化学模拟准确.
结论:
- 对于含有金属的能量化合物,不建议使用Cγ方法.
- 对于有机高爆炸物的高吞吐量设计,Cγ方法是快速,准确的Gurney能量计算的宝贵工具.
- 热化学模拟对于最佳预测气壁速度至关重要.
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