在化聚胺淡化膜中的节点网络增强了水运输
Danyang Li1, Wenkai Liu1, Xiaomao Wang1
1State Key Laboratory of Regional Environment and Sustainability, School of Environment, Tsinghua University, Beijing 100084, China.
Science advances
|May 2, 2025
概括
研究人员可视化了海水淡化膜的水合结构,揭示了对水运输至关重要的结节网络. 这一发现促进了对薄膜复合材料反透膜性能的理解.
科学领域:
- 材料科学 材料科学 材料科学
- 化学工程是化学工程的重要组成部分.
- 环境科学 环境科学
背景情况:
- 薄膜复合材料 (TFC) 逆透 (RO) 膜对于淡化至关重要.
- 它们在水合条件下的聚胺选择性层结构及其对水运输的影响尚未完全理解.
研究的目的:
- 为了阐明商业聚胺膜的三维水合结构.
- 为了将结构特征与膜水运输特性相关联.
主要方法:
- 使用冷电子断层扫描 (cryo-ET) 来重建六种商业聚胺膜的水合结构.
- 分析了聚胺层的结构参数.
- 测量了另外16个膜的水透率.
主要成果:
- 揭示了聚胺选择性层的完全膨胀,异质的结节网络结构.
- 这些结节的厚度约为17.2纳米,直接连接到基质孔隙.
- 关键的节点参数与水的透度有显著的相关性,突出了它们在运输中的作用.
结论:
- 该研究提供了在水合条件下对聚胺膜的详细3D结构理解.
- 这些发现强调了结节网络在淡化过程中控制水运输中的关键作用.
- 这项研究有助于更好地了解RO膜的结构性能关系.
相关概念视频
Dialysis
536
Dialysis is a diffusion-based purification process that separates analyte molecules from a complex matrix. This is accomplished by allowing molecules in the solution to pass through a semipermeable membrane into a liquid on the other side. The membrane is usually made of cellulose acetate or cellulose nitrate, and the second liquid must be miscible with the solution. Ions (e.g., chloride or sodium) or organic molecules (e.g., glucose) can pass through the membrane pores, which generally have...
536
Ion Exchange
395
Ion exchange chromatography separates charged molecules from a solution by reversibly exchanging them with mobile, or 'active', ions associated with the oppositely charged stationary phase. This method can be used to separate ions, soften and deionize water, and purify solutions. The polymers comprising the ion-exchange column are high-molecular-weight and chemically stable polymers, crosslinked to be porous and essentially insoluble. They are also functionalized with either acidic or...
395
Pore Transport and Ion-Pair Transport
291
Pore transport and ion-pair formation are critical mechanisms for the absorption and distribution of drugs in the body.
Pore transport, also known as convective transport, is a process where small molecules like urea, water, and sugars rapidly cross cell membranes as though there were channels or pores in the membrane. Although direct microscopic evidence is limited but the concept of pores or channels is widely accepted based on physiological evidence. Despite the lack of direct...
Pore transport, also known as convective transport, is a process where small molecules like urea, water, and sugars rapidly cross cell membranes as though there were channels or pores in the membrane. Although direct microscopic evidence is limited but the concept of pores or channels is widely accepted based on physiological evidence. Despite the lack of direct...
291


