通过实验证实孔介质中体 (微小和纳米粒子) 运输的拦截历史范式
William P Johnson1, Luis Andres Ullauri1, Bashar M Al-Zghoul2
1University of Utah, Geology and Geophysics, Salt Lake City, Utah 84112, United States.
Environmental science & technology
|May 5, 2025
概括
在不利的条件下,由于多次拦截,合体过理论的偏差会发生. 这项研究揭示了与各种依附历史相关的非指数的保留配置文件,影响着合体运输.
科学领域:
- 环境科学 环境科学
- 合体和表面科学科学
- 地质化学 地质化学
背景情况:
- 体过理论 (CFT) 预测了指数级保留概况 (RP).
- 在不利的条件下,对各种合物 (例如,病原体,工程纳米材料,微/纳米塑料) 观察到CFT,特别是非指数性RP的偏差.
- 不利的条件涉及合物-表面相互作用中的排斥性障碍.
研究的目的:
- 通过实验证明,非指数的RP源于合物拦截历史的变化.
- 为了研究多次拦截对合物保留配置和附着效率的影响.
- 在不利条件下提供对合体运输的基本理解.
主要方法:
- 进行了实验,观察合体的附着和保留.
- 在有利条件和不利条件下分析了合物附着的保留概况 (RPs).
- 研究了单个与多个拦截在合物附着中的作用.
主要成果:
- 在有利条件下粘附的合体的RP是指数的.
- 对于在不利条件下附着的合体,RP是非单调的,表明与CFT的偏差.
- 多次拦截在不利条件下显著促进了合物附着,附着效率 (α) 随着拦截顺序的增加而增加.
结论:
- 非指数式RP是不利条件下的合体运输的一个基本方面,由各种拦截历史驱动.
- 在存在排斥性障碍时,多重拦截在合体保留中发挥着主导作用.
- 这些发现挑战了CFT在复杂环境场景中的普遍适用性.
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