石油漏对煤炭物理化学结构的影响
Haiqing Shuang1,2,3, Xiaoning Yu1,2, Biao Hu1,2,3
1College of Safety Science and Engineering, Xi'an University of Science and Technology, Xi'an 710054, Shaanxi, China.
ACS omega
|May 5, 2025
概括
原油的入简化了煤炭的孔隙结构,降低了气体吸附能力. 这项研究阐明了石油如何影响煤炭储存气体的能力,这对于煤炭和石油矿山至关重要.
科学领域:
- 地质化学 地质化学
- 材料科学 材料科学 材料科学
- 石油工程是石油工程中的一个.
背景情况:
- 煤层经常与原油矿床共存.
- 了解石油浸煤中的气体吸附对于矿山安全和资源管理至关重要.
研究的目的:
- 研究原油入如何影响煤炭的气体吸附性能.
- 阐明这些变化的潜在机制.
主要方法:
- 红外光谱学用于分析原料和油浸煤中的功能组.
- (N2) 吸附实验以确定孔隙碎片尺寸.
- 皮耶索米特入侵实验以表征孔隙结构.
主要成果:
- 经过油浸的煤炭显示基,基碳化合物和氧化功能组的增加,芳香度降低.
- 与原煤相比,与石油浸的煤炭相比,孔隙碎片尺寸 (D1和D2) 减少了.
- 石油入简化了孔隙结构,减少了孔隙复杂性和气体吸附能力.
结论:
- 原油的入侵大大改变了煤炭的化学成分和孔隙结构.
- 观察到的变化导致油浸煤的气体吸附性能下降.
- 这些发现为管理煤炭-石油共存矿区的气体排水提供了基础.
相关概念视频
Physical Properties Affecting Solubility
22.1K
Solutions of Gases in Liquids
As for any solution, the solubility of a gas in a liquid is affected by the attractive intermolecular forces between solute and solvent species. Unlike solid and liquid solutes, however, there is no solute-solute intermolecular attraction to overcome when a gaseous solute dissolves in a liquid solvent since the atoms or molecules comprising a gas are far separated and experience negligible interactions. Consequently, solute-solvent interactions are the sole...
As for any solution, the solubility of a gas in a liquid is affected by the attractive intermolecular forces between solute and solvent species. Unlike solid and liquid solutes, however, there is no solute-solute intermolecular attraction to overcome when a gaseous solute dissolves in a liquid solvent since the atoms or molecules comprising a gas are far separated and experience negligible interactions. Consequently, solute-solvent interactions are the sole...
22.1K
Entropy and Solvation
6.9K
The process of surrounding a solute with solvent is called solvation. It involves evenly distributing the solute within the solvent. The rule of thumb for determining a solvent for a given compound is that like dissolves like. A good solvent has molecular characteristics similar to those of the compound to be dissolved. For example, polar solutions dissolve polar solutes, and apolar solvents dissolve apolar solutes. A polar solvent is a solvent that has a high dielectric constant (ϵ...
6.9K
Physical Properties of Alkanes
10.6K
Alkanes are nonpolar molecules due to the presence of only carbon and hydrogen atoms. The electronegativity difference between carbon and hydrogen is minimal, and hence alkanes have a zero dipole moment. This leads to the presence of only dispersion forces between the molecules. The strength of dispersion forces is dependent on the surface area of the molecules on which they act. Since the surface area increases with the molecular length for straight-chain alkanes, the dispersion forces also...
10.6K
Extraction: Advanced Methods
388
Metal ions can be separated from one another by complexation with organic ligands–the chelating agent– to form uncharged chelates. Here, the chelating agent must contain hydrophobic groups and behave as a weak acid, losing a proton to bind with the metal. Since most organic ligands used in this process are insoluble or undergo oxidation in the aqueous phase, the chelating agent is initially added to the organic phase and extracted into the aqueous phase. The metal-ligand complex is...
388
Solubility
17.1K
Solution, Solubility, and Solubility Equilibrium
A solution is a homogeneous mixture composed of a solvent, the major component, and a solute, the minor component. The physical state of a solution—solid, liquid, or gas—is typically the same as that of the solvent. Solute concentrations are often described with qualitative terms such as dilute (of relatively low concentration) and concentrated (of relatively high concentration).
In a solution, the solute particles (molecules,...
A solution is a homogeneous mixture composed of a solvent, the major component, and a solute, the minor component. The physical state of a solution—solid, liquid, or gas—is typically the same as that of the solvent. Solute concentrations are often described with qualitative terms such as dilute (of relatively low concentration) and concentrated (of relatively high concentration).
In a solution, the solute particles (molecules,...
17.1K
Combustion Energy: A Measure of Stability in Alkanes and Cycloalkanes
6.2K
The low reactivity in alkanes can be attributed to the non-polar nature of C–C and C–H σ bonds. Alkanes, therefore, were initially termed as “paraffins,” derived from the Latin words: parum, meaning “too little,” and affinis, meaning “affinity.”
Alkanes undergo combustion in the presence of excess oxygen and high-temperature conditions to give carbon dioxide and water. A combustion reaction is the energy source in natural gas, liquified...
Alkanes undergo combustion in the presence of excess oxygen and high-temperature conditions to give carbon dioxide and water. A combustion reaction is the energy source in natural gas, liquified...
6.2K


