粉作为硬碳阳极的有效前体,可以实现高性能离子储存
Yuyang Pan1,2, Zhihao Li1,2, Rui Fang1,2
1School of Materials Science and Engineering, Xihua University Chengdu Sichuan 610039 China btz123@foxmail.com.
RSC advances
|May 7, 2025
概括
研究人员开发了一种新的方法来稳定粉,用于离子电池中的硬碳阳极. 这种方法可以防止前体泡,使高容量和稳定的性能成为具有成本效益的储能应用.
科学领域:
- 材料科学 材料科学 材料科学
- 电化学 电化学 电化学
- 储能 储能 储能 储能 储能 储能
背景情况:
- 粉是离子电池中硬碳阳极的有前途的前体,因为粉的丰富性和高碳含量.
- 然而,粉在热解过程中倾向于融化和泡,这限制了它的产量和实际应用.
研究的目的:
- 开发一种方法来抑制粉在热解过程中的泡,以改善硬碳阳极的生产.
- 为了提高粉衍生的硬碳的储存性能.
主要方法:
- 粉的化和交叉连接使用烯树脂和氨酸无水化.
- 改性粉复合物的热解以产生硬碳.
- 在离子电池中,硬碳作为阳极的电化学特征.
主要成果:
- 通过复合前体的协同作用,成功抑制了粉泡.
- 准备好的硬碳呈现出丰富的微孔/半孔和更大的微晶结构.
- 高特异性容量 (342.28 mA hg-1),优异的初始放电容量 (85.89%) 和显著的容量保留 (87.24%在100个循环后).
- 优异的速度性能,容量恢复率为95.11%.
结论:
- 稳定粉衍生的硬碳阳极提供高储存性能和成本效益.
- 这种方法显示出大规模商业化基阳极用于离子电池的巨大潜力.
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