测量非同质流体的蒸曲线:两种热解油的方法和案例研究
Megan E Harries1, Armando G McDonald2, Thomas J Bruno1
1Applied Chemicals and Materials Division, Material Measurement Laboratory, National Institute of Standards and Technology, Boulder, CO 80305.
概括
研究人员开发了一种新方法来准确测量非均燃料的挥发性,比如与水混合的原油热解油. 这可以更好地与现有的燃料数据进行比较.
科学领域:
- 燃料科学 燃料科学 燃料科学
- 化学工程是化学工程的重要组成部分.
- 分析化学 分析化学
背景情况:
- 在燃料研究中,波动性至关重要,它会影响性能,并对混合物成分敏感.
- 蒸曲线是用于测量燃料挥发性的标准实验室方法.
- 不同质的流体,特别是具有多个液相的流体,对传统的蒸分析构成挑战.
研究的目的:
- 开发和介绍一种数据分析方法,以弥补燃料样本的非同质性.
- 为了能够准确地测量多相原油热解油的挥发性.
- 为了方便分析的有机相与已建立的石油和热解油数据进行比较.
主要方法:
- 使用高级蒸曲线 (ADC) 方法分析燃料样本.
- 专注于含有显著水性和有机相的原始热解油.
- 开发了一种特定的数据分析技术,以纠正相位分离和非同质性.
主要成果:
- 成功分析了不均的原始热解油的挥发性.
- 新方法有效地弥补了分离的水性和有机相的存在.
- 能够与现有的数据集可靠地比较有机阶段的挥发性特征.
结论:
- 提出的数据分析方法提高了复杂燃料混合物的挥发性测量的准确性.
- 这种方法对于理解和利用像热解油这样的替代燃料至关重要.
- 提高燃料挥发性的特征有助于燃料研究和开发的进步.
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