化作为K离子电池的正极材料
Kazushi Magara1, Tomooki Hosaka1, Ryoichi Tatara1
1Department of Applied Chemistry, Tokyo University of Science, 1-3 Kagurazaka, Shinjuku, Tokyo 162-8601, Japan.
ACS applied materials & interfaces
|May 7, 2025
概括
在离子电池中测试了化的化. K3VF6显示出高容量的承诺,但结构稳定性是未来高性能化物材料的关键.
科学领域:
- 材料科学 材料科学 材料科学
- 电化学 电化学 电化学
- 无机化学 无机化学
背景情况:
- 离子电池 (KIB) 是离子电池的一个有希望的替代品.
- 开发高效的正极材料对于推进KIB技术至关重要.
- 以化物为基础的材料由于其高的理论容量而具有潜力.
研究的目的:
- 调查的化物 (KxVnFm) 作为KIBs的潜在正极材料.
- 评估K5V3F14,K3VF6和KVF4.4的电化学性能.
- 了解结构稳定性和电化学活性之间的关系.
主要方法:
- 在离子电池中对K5V3F14,K3VF6和KVF4进行电化学测试.
- 射线吸收光谱 (XAS) 用于分析的氧化状态.
- 在离子插入/提取过程中对结构变化的分析.
主要成果:
- K5V3F14和KVF4显示出有限的电化学活性 (∼50 mAh g-1).
- K3VF6以3.7V平原和95mAhg-1初始容量表现出卓越的性能.
- 在K3VF6中,XAS证实了可逆的V4+/3+过程,但V4+/5+氧化在很大程度上是不可逆的.
- 在显著的提取后,K3VF6经历了不可逆转的结构变化.
结论:
- 由于其电化学性能,K3VF6是KIB的有希望的阴极材料.
- 结构的不稳定性,特别是在大量的离子被去除后,限制了容量.
- 设计具有增强结构完整性的化物材料对于高容量KIB至关重要.
相关概念视频
Electrolytes: van't Hoff Factor
32.6K
Colligative Properties of Electrolytes
The colligative properties of a solution depend only on the number, not on the identity, of solute species dissolved. The concentration terms in the equations for various colligative properties (freezing point depression, boiling point elevation, osmotic pressure) pertain to all solute species present in the solution. Nonelectrolytes dissolve physically without dissociation or any other accompanying process. Each molecule that dissolves yields one...
The colligative properties of a solution depend only on the number, not on the identity, of solute species dissolved. The concentration terms in the equations for various colligative properties (freezing point depression, boiling point elevation, osmotic pressure) pertain to all solute species present in the solution. Nonelectrolytes dissolve physically without dissociation or any other accompanying process. Each molecule that dissolves yields one...
32.6K
Alkali Metals
19.0K
Group 1 elements are soft and shiny metallic solids. They are malleable, ductile, and good conductors of heat and electricity. The melting points of the alkali metals are unusually low for metals and decrease going down the group, while the density increases going down the group with the exception of potassium (Table 1).
Table 1: Properties of the alkali metals
Table 1: Properties of the alkali metals
19.0K
Electrolysis
25.9K
In a galvanic cell, the electrical work is done by a redox system on its surroundings as electrons produced by the spontaneous redox reactions are transferred through an external circuit. Alternatively, an external circuit does work on a redox system by imposing a voltage sufficient to drive an otherwise nonspontaneous reaction in a process known as electrolysis. For instance, recharging a battery involves the use of an external power source to drive the spontaneous (discharge) cell reaction in...
25.9K
Ionic Bonding and Electron Transfer
40.5K
Ions are atoms or molecules bearing an electrical charge. A cation (a positive ion) forms when a neutral atom loses one or more electrons from its valence shell, and an anion (a negative ion) forms when a neutral atom gains one or more electrons in its valence shell. Compounds composed of ions are called ionic compounds (or salts), and their constituent ions are held together by ionic bonds: electrostatic forces of attraction between oppositely charged cations and anions.
40.5K
Batteries and Fuel Cells
26.8K
A battery is a galvanic cell that is used as a source of electrical power for specific applications. Modern batteries exist in a multitude of forms to accommodate various applications, from tiny button batteries such as those that power wristwatches to the very large batteries used to supply backup energy to municipal power grids. Some batteries are designed for single-use applications and cannot be recharged (primary cells), while others are based on conveniently reversible cell reactions that...
26.8K
Ions and Ionic Charges
66.2K
In ordinary chemical reactions, the nucleus — which contains the protons and neutrons of each atom and thus identifies the element — remains unchanged. Electrons, however, can be added to atoms by transfer from other atoms, lost by transfer to other atoms, or shared with other atoms. The transfer and sharing of electrons among atoms govern the chemistry of the elements. During the formation of some compounds, atoms gain or lose electrons to form electrically charged particles called...
66.2K


