Y3+兴奋剂对CuCrO微观结构和磁性转变的影响2陶
Haibo Lin1, Shanshan Ye1, Guozhu Xiong1
1School of Physical Science and Technology, Guangxi University, 100 East Daxue Road, Nanning 530004, China.
Materials (Basel, Switzerland)
|May 7, 2025
概括
在CuCrO陶中 (Y3+) 兴奋剂影响微观结构和磁性. 兴奋剂增强了反铁磁性,但降低了它的稳定性,影响了磁性相位过渡.
科学领域:
- 材料科学 材料科学 材料科学
- 固态化学 固态化学
- 磁力学 磁力学 是一种
背景情况:
- 铜色胺 (CuCrO2) 具有抗铁磁性质.
- 了解兴奋剂对这些特性的影响对于材料开发至关重要.
研究的目的:
- 调查Y3+兴奋剂对CuCrO的微观结构和反铁磁相过渡的影响.
- 探索Y3+替换如何影响磁性易感性和尼尔温度 (TN).
主要方法:
- 固态反应方法用于合成不同Y3+度 (x = 0-0.02) 的陶样品.
- 通过温度依赖的灵敏度测量,对微观结构变化 (单元细胞体积,颗粒大小) 和磁性特性进行系统的研究.
主要成果:
- Y3+兴奋剂增加了单元细胞体积和平均粒径.
- 所有样本都表现出140K以上的偏磁性,在冷却后转变为反铁磁性.
- 兴奋剂改变了Cr-O-Cr键的角度和长度,影响了超交换相互作用.
- 尼尔温度 (TN) 在Y3+兴奋剂下降,表明反铁磁稳定性减弱.
结论:
- 在CuCrO中Y3+的兴奋剂2增强了反铁磁的排序,但降低了它的稳定性.
- 兴奋剂诱导的微观结构变化在调节磁性相位过渡中起着关键作用.
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