在固化和老化过程中Fe含量对Sm-Co-Fe合金相位行为的影响
Zhi Zhu1, Yikun Fang2, Wei Wu1
1Metallurgical Technology Institute, Central Iron and Steel Research Institute Co., Ltd., Beijing 100081, China.
Materials (Basel, Switzerland)
|May 7, 2025
概括
本研究研究了铁 (Fe) 含量对萨马--铁 (Sm-Co-Fe) 合金固化阶段的影响. 增加Fe含量会影响阶段形成,特别是减少SmCo5阶段并影响SmCo5和Sm2Co17阶段的共存.
科学领域:
- 材料科学 材料科学 材料科学
- 金工业是金工业的一个方面.
- 固化科学 固化科学
背景情况:
- - (Sm-Co) 合金对于高性能磁铁至关重要.
- 了解Sm-Co-Fe三元合金中的相位形成对于优化磁性属性至关重要.
- 铁 (Fe) 对固化行为的影响需要详细的研究.
研究的目的:
- 为了研究不同铁含量对Sm25.5Co的固化和老化阶段的影响.
- 用热力学模型分析合金原子之间的相互作用.
- 为开发2:17型Sm-Co磁性材料提供基础.
主要方法:
- 合金化使用非消耗性真空弧形炉.
- 在固化和12小时在1143°C老化后进行相位分析.
- 应用Cai Li修改的Miedema模型和Toop几何模型用于热力学计算.
主要成果:
- 预测Sm-Co和Sm-Co-Fe原子之间存在强烈的原子相互作用,促进金属间化合物形成.
- 随着Fe含量的增加,SmCo5阶段的减少,在25%的Fe中消失.
- SmCo5和Sm2Co17相的共存区域随着Fe含量增加而减少,并且在25%的重量%上不存在Fe.
结论:
- 铁含量显著影响Sm-Co-Fe合金的固化和老化阶段.
- 实验阶段结果与热力学模型预测一致.
- 这项研究支持开发先进的2:17型Sm-Co磁性材料.
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