来自煤河的酸盐水合物和酸盐水合物的合成,表征和凝固活性
Qing Zhang1,2, Xianglin Zhang1, Lulu Wang1
1School of Resource and Environmental Engineering, Anhui Water Conservancy Technical College, Hefei 231603, China.
Molecules (Basel, Switzerland)
|May 7, 2025
概括
煤废物可以转化为有价值的酸水合物 (M-S-H) 和酸水合物 (C-S-H) 凝固材料. 该工艺采用复合材料激活处理,产生具有出色吸附性能的材料.
科学领域:
- 材料科学 材料科学 材料科学
- 环境工程 环境工程
- 化学工程是化学工程的重要组成部分.
背景情况:
- 煤炭污水是主要的工业固体废物,由于产量大,造成了环境挑战.
- 它含有有价值的二氧化和,为资源回收和价值化提供了机会.
- 从废物中开发可持续的水泥材料对于循环经济原则至关重要.
研究的目的:
- 从煤炭中合成酸水合物 (M-S-H) 和酸水合物 (C-S-H).
- 为了研究机械热化学复合物激活对煤的固性质的影响.
- 描述合成的M-S-H和C-S-H,以鉴于它们作为中孔吸附剂的潜力.
主要方法:
- 使用机械热化学复合激活方法处理了煤炭.
- 通过感应合等离子体原子发射光谱学 (ICP-AES),里埃变换红外光谱学 (FTIR),X射线衍射 (XRD),扫描电子显微镜 (SEM) 和差分扫描热度计-热重度计分析 (DSC-TG) 分析了水泥活动.
- 系统地研究了影响活动的关键因素,包括化参数和摩尔比率 (Ca/Si,Mg/Si).
主要成果:
- 烧焦的温度,时间以及Ca/Si和Mg/Si的摩尔比率显著影响了煤团的化活性.
- 活动与Si4+和Al3+的溶解有正相关,高峰时是考林完全分解成活性SiO2和Al2O3.
- M-S-H和C-S-H在室温下在7天内成功合成,表现出高特异性表面积,良好的机械性能和发达的孔隙结构.
结论:
- 煤可以有效地用作合成M-S-H和C-S-H水泥材料的前体.
- 复合活性化方法显著提高了煤的反应性,并缩短了合成时间.
- 合成的M-S-H和C-S-H由于其结构特征,是金属离子吸附的有希望的中孔材料.
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