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Catalysis02:50

Catalysis

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The presence of a catalyst affects the rate of a chemical reaction. A catalyst is a substance that can increase the reaction rate without being consumed during the process. A basic comprehension of a catalysts’ role during chemical reactions can be understood from the concept of reaction mechanisms and energy diagrams.
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Oxidation of Alkenes: Syn Dihydroxylation with Osmium Tetraoxide02:44

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Alkenes are converted to 1,2-diols or glycols through a process called dihydroxylation. It involves the addition of two hydroxyl groups across the double bond with two different stereochemical approaches, namely anti and syn. Dihydroxylation using osmium tetroxide progresses with syn stereochemistry.
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Catalytic hydrogenation of alkenes is a transition-metal catalyzed reduction of the double bond using molecular hydrogen to give alkanes. The mode of hydrogen addition follows syn stereochemistry.
The metal catalyst used can be either heterogeneous or homogeneous. When hydrogenation of an alkene generates a chiral center, a pair of enantiomeric products is expected to form. However, an enantiomeric excess of one of the products can be facilitated using an enantioselective reaction or an...
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作为氧化物进化的催化剂的FeHf二元氧/氧化物纳米结构.

Biswaranjan D Mohapatra1, Mateusz Szczerba1,2, Joanna Czopor1

  • 1Department of Physical Chemistry and Electrochemistry, Faculty of Chemistry, Jagiellonian University, Gronostajowa 2, 30-387 Krakow, Poland.

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脉冲电沉积 (PED) 能够控制铁-哈夫二元氧化物/氧化物 (FeHf-BH) 纳米复合物的合成. 优化的FeHf-BH材料显示出有希望的氧化演化反应 (OER) 催化活性.

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科学领域:

  • 材料科学 材料科学 材料科学
  • 电化学 电化学 电化学
  • 纳米技术 纳米技术

背景情况:

  • 开发高效的电催化剂对于能源转换技术至关重要.
  • 金属氧化物/氧化物是氧化演化反应 (OER) 的有希望的候选物.
  • 控制合成的多金属纳米复合材料是一个挑战.

研究的目的:

  • 为合成FeHf-BH纳米复合材料提供脉冲电沉积 (PED).
  • 为了证明沉积材料中Fe和Hf含量的受控变化.
  • 为了研究FeHf-BH纳米复合材料的OER活性.

主要方法:

  • 来自酸盐水浴的脉冲电位 (PED).
  • 使用SEM,EDS,XRD,Raman和XPS进行表征.
  • 在性介质中对氧化演化反应 (OER) 的电化学分析.

主要成果:

  • 控制的Fe (5.9-49.9%) 和Hf (2.4-58.7%) 含量已经实现.
  • 沉积的材料是聚合的纳米粒子 (50-150 nm).
  • 优化的FeHf-BH (11.9 at.% Hf) 显示出极好的OER活动 (1.63V开始,47mV/dec Tafel斜率).

结论:

  • PED是一种可扩展的方法来设计FeHf-BH纳米复合材料.
  • FeHf-BH 材料具有高的 OER 性能.
  • 这种方法可以扩展到其他多金属氧化物/氧化物系统.