一种相位过渡的离子液体赋予基于COF的混合矩阵膜高效的CO2分离能力
Shuyu Guo1, Jingrao He1, Hailong Han1
1Hunan Key Laboratory of Micro & Nano Materials Interface Science, College of Chemistry and Chemical Engineering, Central South University, Changsha, 410083, China. shaigu@csu.edu.cn.
概括
热敏的离子液体改善了基于COF的膜,以提高二氧化碳的分离. 新型IL@DAAQ-COF材料实现了高的二氧化碳透性和选择性,超过了性能基准.
科学领域:
- 材料科学 材料科学 材料科学
- 化学工程是化学工程的重要组成部分.
- 分离技术 分离技术
背景情况:
- 基于COF的混合矩阵膜 (MMM) 在气体分离方面表现有前途.
- 接口兼容性问题往往限制了基于COF的MMM的性能.
- 离子液体 (ILs) 为材料修饰提供可调节的特性.
研究的目的:
- 为了提高基于COF的MMM的界面兼容性.
- 使用热敏离子液体提高二氧化碳分离性能.
- 研究ILs在调节COF通道和CO2亲和力中的作用.
主要方法:
- 在现场合成IL@DAAQ-COF.
- 将热敏相变离子液体纳入COF结构.
- 用于CO2/N2分离的膜性质的表征.
主要成果:
- 显著提高了基于COF的MMM的界面兼容性.
- IL@DAAQ-COF 的二氧化碳透率为 17.449 巴雷尔.
- 实现了27.2的CO2 / N2选择性,超过了2019年詹森/麦克凯恩上限.
结论:
- 热敏离子液体有效地改善了基于COF的MMM.
- 该IL@DAAQ-COF展示了卓越的二氧化碳捕获能力.
- 这种方法为先进的气体分离膜提供了一个有希望的途径.
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