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Updated: May 16, 2025

Vibrational Spectra of a N719-Chromophore/Titania Interface from Empirical-Potential Molecular-Dynamics Simulation, Solvated by a Room Temperature Ionic Liquid
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Vibrational Spectra of a N719-Chromophore/Titania Interface from Empirical-Potential Molecular-Dynamics Simulation, Solvated by a Room Temperature Ionic Liquid

Published on: January 25, 2020

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通过调制库伦比合,加速对称性破坏的电荷分离,以角式与线性烯二胺二胺二聚体相比,通过调节库伦比合

Aniruddha Mazumder1, Kavya Vinod1, Aivin Chemmarappallil Thomas1

  • 1School of Chemistry, Indian Institute of Science Education and Research Thiruvananthapuram, Maruthamala P.O., Vithura, Thiruvananthapuram, Kerala, India 695551.

The journal of physical chemistry letters
|May 8, 2025
PubMed
概括

有机 პერიlenediimide 二度体显示取决于方向的电荷分离. 角二极管实现了超快速的对称性破坏电荷分离,比线性二极管快得多,有助于光采集材料设计.

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Spatial Separation of Molecular Conformers and Clusters10:37

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¹H NMR: Complex Splitting

A proton M that is coupled to a proton X results in doublet signals for M. However, NMR-active nuclei can be simultaneously coupled to more than one nonequivalent nucleus. When M is coupled to a second proton A, such as in styrene oxide, each peak in the doublet is split into another doublet.
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The coupling interactions of nuclei across four or more bonds are usually weak, with J values less than 1 Hz. While these are usually not observed in spectra, the presence of multiple bonds along the coupling pathway can result in observable long-range coupling.
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