毒书:对疑似旧书中的23个元素进行首次全面分析
Teresa Cecchi1, Deborha Dorotei2, Maria Chiara Leonori2
1Istituto Tecnico Tecnologico (ITT) "G. e M. Montani", Via Montani 7, I-63900 Fermo, Italy.
The Science of the total environment
|May 8, 2025
概括
和铜等危险的有毒金属存在于19世纪的绿色书籍中,构成了bibliotoxicology风险. 保护措施对于处理这些历史文件至关重要.
科学领域:
- 遗产科学科学 遗产科学
- 分析化学 分析化学
- 毒理学 毒理学 毒理学
背景情况:
- 历史的工业实践在文化遗产中留下有毒的残留物,包括书籍.
- 圣经毒理学是一个新兴的问题,需要对遗产藏品中的有毒金属进行定量分析.
- 国际毒本项目在历史绿色书籍中发现了潜在的.
研究的目的:
- 对19世纪和20世纪初的绿色图书进行全面的定性和定量多元元素分析.
- 调查历史书籍中作为颜料使用的有毒金属的存在和类型.
- 为评估遗产图书馆中与有毒金属相关的职业健康风险建立定量基准.
主要方法:
- 感应合等离子光学发射光谱 (ICP-OES) 用于多元件分析.
- 对三十本历史绿皮书进行定性和定量元素分析.
- 软体测量分析以确定颜料成分和化学性质.
主要成果:
- ,,,,和的无处不在存在;铜和铁在所有分析的绿色书中都存在.
- 只有一本书含有与巴黎绿色相一致的比例的铜和.
- 标识的颜料来源:碳酸,氧化,硫酸,绿 (色和普鲁士蓝).
结论:
- 历史绿色书籍可能含有危险的有毒金属,需要小心处理和储存.
- 对金属分析的定量方法对于理解遗产遗址中的生物毒理学风险至关重要.
- 建议包括限制访问,保护措施和对含有有毒金属的容量提供明确的用户信息.
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