评估LA-ICP-MS对具有石灰质骨的生物体进行定量成像的坚实标准:准确性,均性和激光波长效应
Ewelina Pollak-Kowa1,2, Anna Telk1, Marcin Wieczorek1
1Jagiellonian University, Faculty of Chemistry, Gronostajowa St 2, 30-387 Cracow, Poland. anna.telk@uj.edu.pl.
The Analyst
|May 9, 2025
概括
选择正确的固体标准对于准确的LA-ICP-MS分析石灰质生物来说至关重要. 这项研究评估了各种标准,提供了对海洋化物可靠元素成像的见解.
科学领域:
- 地质化学 地质化学
- 古生物学的古生物学
- 分析化学 分析化学
背景情况:
- 激光诱导分解光谱 (LA-ICP-MS) 对于化生物体的元素分析至关重要.
- 现有的固体标准 (玻璃,石颗粒) 存在矩阵匹配挑战和同质性问题.
- 石灰质骨的LA-ICP-MS研究中经常缺乏准确性验证.
研究的目的:
- 评估各种固体标准对石灰质生物的定量元素成像的有效性.
- 评估标准矩阵,激光波长和内部标准化对分析准确性的影响.
- 描述新型液体粉末标准的同质性和制备可重复性.
主要方法:
- 在珊瑚藻和藻中分析,和,使用LA-ICP-MS.
- 对比NIST 610/612玻璃标准,基于酸盐的颗粒和Cerastoderma glaucum贝粉标准.
- 研究激光波长和内部标准化对准确度的影响.
主要成果:
- 固体标准的矩阵显著影响元素定量化的准确性.
- 激光波长和内部标准化方法可以影响LA-ICP-MS结果的可靠性.
- 新的液体粉末标准证明了特征的同质性和制备的可重复性.
结论:
- 精心选择固体标准对于精确的LA-ICP-MS分析石灰质标本至关重要.
- 对于可靠的元素成像,需要矩阵匹配标准或适当的校准策略.
- 这项研究为改善海洋化物中LA-ICP-MS定量分析提供了基础.
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