在-40°C下通过操纵电解质平衡来启动的>200Wh kg-1无阳极Na袋电池
Qiaonan Zhu1, Jiawei Wang2, Liqiang Wu3
1School of Chemistry, Beihang University, Beijing 100191, China.
National science review
|May 9, 2025
概括
研究人员开发了一种用于寒冷气候的高能量密度无阳极电池. 优化的电解质能够在-40°C下稳定运行,为低温可充电电池实现了创纪录的能量密度.
科学领域:
- 材料科学 材料科学 材料科学
- 电化学 电化学 电化学
- 储能 储能 储能 储能 储能 储能
背景情况:
- 低温能量密度电池对于寒冷气候应用至关重要.
- 无阳极电池配置提供了增加能量密度的潜力.
- 低温无阳极电池面临着电解质兼容性和高压稳定性的挑战.
研究的目的:
- 开发一种高能量密度的无阳极电池,能够在低温下工作.
- 为解决低温,高压应用中电解质性能的局限性.
- 为了提高无阳极电池的低温动力学和高压稳定性.
主要方法:
- 使用了电解质关联-解离平衡调节.
- 优化侧重于促进离子溶解和形成稳定的介面相.
- 电化学性能在-40°C使用无阳极电池进行评估.
主要成果:
- 在-40°C下实现高库伦比克效率 (99.90%) 的涂/脱落.
- 在低温下证明了电解质 (>4.3V) 的广泛的电化学稳定性窗口.
- 一个没有阳极的Al@C能量NaNi1/3Fe1/3Mn1/3O2袋式电池在-40°C时达到创纪录的能量密度204Wh kg−1.
结论:
- 电解质优化策略成功实现了低温无阳极电池的高能量密度运行.
- 这一突破解决了开发适用于极端环境的强大的电解质的关键挑战.
- 对于用于寒冷气候应用的能量密集电池来说,这代表了重大进步.
相关概念视频
Energy Associated With a Charge Distribution
1.5K
The work done to bring a charge through a distance r is given by the potential difference between the initial and the final position. To assemble a collection of point charges, the total work done can be expressed in terms of the product of each pair of charges divided by their separation distance, defined with respect to a suitable origin. Solving this expression gives the energy stored in a point charge distribution.
1.5K
Batteries and Fuel Cells
26.7K
A battery is a galvanic cell that is used as a source of electrical power for specific applications. Modern batteries exist in a multitude of forms to accommodate various applications, from tiny button batteries such as those that power wristwatches to the very large batteries used to supply backup energy to municipal power grids. Some batteries are designed for single-use applications and cannot be recharged (primary cells), while others are based on conveniently reversible cell reactions that...
26.7K
Strain-Energy Density
318
Understanding the strain energy density in materials under axial load is crucial for evaluating their mechanical behavior and durability. When a rod is subjected to such a load, it elongates and stores energy, known as strain energy, as potential energy within the material. This energy is measured in terms of energy per unit volume.
In the elastic region of a material, the relationship between the stress and the strain is linear and follows Hooke's Law. The strain energy density in this...
In the elastic region of a material, the relationship between the stress and the strain is linear and follows Hooke's Law. The strain energy density in this...
318
Energy Stored in Inductors
260
An inductor is ingeniously crafted to accumulate energy within its magnetic field. This field is a direct result of the current that meanders through its coiled structure. When this current maintains a steady state, there is no detectable voltage across the inductor, prompting it to mimic the behavior of a short circuit when faced with direct current.
In terms of gauging the energy stored within an inductor, it is equivalent to the integral of the power delivered at every individual moment, all...
In terms of gauging the energy stored within an inductor, it is equivalent to the integral of the power delivered at every individual moment, all...
260
Energy Carried By Electromagnetic Waves
2.8K
Anyone who has used a microwave oven knows there is energy in electromagnetic waves. Sometimes, this energy is obvious, such as in the summer sun's warmth. At other times, it is subtle, such as the unfelt energy of gamma rays, which can destroy living cells. Electromagnetic waves bring energy into a system through their electric and magnetic fields. These fields can exert forces and move charges in the system and, thus, do work on them. However, there is energy in an electromagnetic wave,...
2.8K
Energy Stored in Capacitors
391
A parallel plate capacitor, when connected to a battery, develops a potential difference across its plates. This potential difference is key to the operation of the capacitor, as it determines how much electrical energy the capacitor can store.
By integrating the equation that relates voltage and current in a capacitor, one can derive an equation for the voltage across the capacitor at any given time. This equation is crucial in understanding and predicting the behavior of capacitors in...
By integrating the equation that relates voltage and current in a capacitor, one can derive an equation for the voltage across the capacitor at any given time. This equation is crucial in understanding and predicting the behavior of capacitors in...
391


