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相关概念视频

Alkali Metals03:06

Alkali Metals

19.0K
Group 1 elements are soft and shiny metallic solids. They are malleable, ductile, and good conductors of heat and electricity. The melting points of the alkali metals are unusually low for metals and decrease going down the group, while the density increases going down the group with the exception of potassium (Table 1).
Table 1: Properties of the alkali metals
19.0K
Ion Exchange01:17

Ion Exchange

421
Ion exchange chromatography separates charged molecules from a solution by reversibly exchanging them with mobile, or 'active', ions associated with the oppositely charged stationary phase. This method can be used to separate ions, soften and deionize water, and purify solutions. The polymers comprising the ion-exchange column are high-molecular-weight and chemically stable polymers, crosslinked to be porous and essentially insoluble. They are also functionalized with either acidic or...
421
Complexation Equilibria: Factors Influencing Stability of Complexes01:09

Complexation Equilibria: Factors Influencing Stability of Complexes

304
In complexation reactions, metal cations are the electron pair acceptors, and the ligands are the electron pair donors. The stability of the metal complexes depends primarily on the complexing ability of the central metal ion and the nature of the ligands. Generally, the complexing ability of the metal ion depends on the size and charge of the ion. As the metal ion size increases, the stability of the metal complexes decreases, provided that the valency of the metal ion and the ligands remain...
304
Ionic Strength: Effects on Chemical Equilibria01:19

Ionic Strength: Effects on Chemical Equilibria

1.3K
The addition of an inert ionic compound increases the solubility of a sparingly soluble salt. For example, adding potassium nitrate to a saturated solution of calcium sulfate significantly enhances the solubility of calcium sulfate. Le Châtelier's principle cannot predict this shift in the equilibrium. Instead, this could be explained in terms of changes in the effective concentration of the ions in solution in the presence of added inert salt.
In this solution, the primary...
1.3K
Ionic Bonds00:42

Ionic Bonds

117.4K
Overview
When atoms gain or lose electrons to achieve a more stable electron configuration they form ions. Ionic bonds are electrostatic attractions between ions with opposite charges. Ionic compounds are rigid and brittle when solid and may dissociate into their constituent ions in water. Covalent compounds, by contrast, remain intact unless a chemical reaction breaks them.
Opposing Charges Hold Ions Together in Ionic Compounds
Ionic bonds are reversible electrostatic interactions between ions...
117.4K
Ionic Crystal Structures02:42

Ionic Crystal Structures

14.0K
Ionic crystals consist of two or more different kinds of ions that usually have different sizes. The packing of these ions into a crystal structure is more complex than the packing of metal atoms that are the same size.
Most monatomic ions behave as charged spheres, and their attraction for ions of opposite charge is the same in every direction. Consequently, stable structures for ionic compounds result (1) when ions of one charge are surrounded by as many ions as possible of the opposite...
14.0K

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相关实验视频

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Solid-state Graft Copolymer Electrolytes for Lithium Battery Applications
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Solid-state Graft Copolymer Electrolytes for Lithium Battery Applications

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一个核心外结构的阿吉罗狄特类型电解质,使化学/电化学稳定性提高.

Shijie Lu1, Yuxiang Zhang1, Haijian Lv1

  • 1School of Materials Science and Engineering, Beijing Institute of Technology, Beijing, 10081, P.R. China.

Angewandte Chemie (International ed. in English)
|May 9, 2025
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概括

这项研究开发了一种新的核心硫化物固体电解质,为全固态电池增强了化学和电化学稳定性. 该工程材料通过氧化阴极实现了高离子导电性和出色的循环性能.

关键词:
阿尔吉罗酸电解质的电解质是阿尔吉罗酸.化学稳定性 化学稳定性核心外结构 核心外结构湿透镜外是一种高度外.界面兼容性 界面兼容性

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科学领域:

  • 材料科学 材料科学 材料科学
  • 电化学 电化学 电化学
  • 固态化学 固态化学

背景情况:

  • 硫化物固体电解质为所有固态电池提供高离子导电性.
  • 化学和电化学稳定性不佳限制了它们的大规模应用.

研究的目的:

  • 开发一种稳定且高导电性的硫化物固体电解质.
  • 为了提高全固态电池的电化学性能.

主要方法:

  • 制造一个核心外固体电解质与Cl梯度的 argyrodite核心和LiCl外.
  • 固体电解质的表面工程.
  • 使用LiCoO2阴极和Li金属阳极进行电化学测试.

主要成果:

  • 达到10.62mS cm-1.1的高离子导电性.
  • 在暴露在空气中的情况下,证明了显著的化学稳定性.
  • 具有优异的电化学稳定性 (0-5V与Li/Li+相比) 和与Li金属的良好兼容性.
  • LiCoO2//固体电解质//Li电池显示95.6%的容量保留超过500个周期在1C.

结论:

  • 核心外结构有效地提高了化学和电化学稳定性.
  • 表面工程协同改善Li+运输和离子导电性.
  • 开发的固体电解质显示出高性能全固态电池的巨大潜力.