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增强化合物异质连接太阳能电池,使用添加的MoOX作为孔运输层
Hongbo Cai1, Xiqi Yang1, Xiaofei Xu1
1College of Materials Science and Engineering, Beijing Key Lab of Microstructure and Properties of Advanced Materials, Beijing University of Technology, Beijing, 100124, P. R. China.
概括
在三氧化物 (MoOX) 中的兴奋剂通过提高载体选择性来增强晶 (c-Si) 太阳能电池. 这种兴奋剂抑制了氧气空缺,提高了效率,减少了光学损失,以获得更好的光伏技术.
科学领域:
- 材料科学 材料科学 材料科学
- 固态物理 固态物理
- 太阳能光伏发电是如何实现的
背景情况:
- 晶体 (c-Si) 太阳能电池是市场的领导者,推动对高效,环保的复合太阳能电池的需求.
- 载体选择性被动接触对于提高c-Si太阳能电池性能至关重要.
研究的目的:
- 研究氧气空缺 (VO) 和 (V) 兴奋剂对三氧化 (MoOX) 的影响.
- 分析这些修改对MoOX特性和c-Si太阳能电池性能的影响.
主要方法:
- 采用第一原则计算来建模缺陷行为和材料特性.
- 使用设备模拟来评估对c-Si太阳能电池的性能影响.
主要成果:
- 氧气空缺 (VO) 迁移到具有低能量屏障 (1.7 eV) 的表面,显著减少了MoOX的工作功能.
- 兴奋剂抑制了VO迁移,增加了0.26 eV的工作功能,并将带隙扩大了0.6 eV.
- 作为照明侧的孔输送层,V-doped MoOX 提高了1.0%的绝对效率,这是由于更高的工作功能和减少的光学损失.
结论:
- 添加的MoOX是一种增强c-Si化合物太阳能电池性能的有希望的材料.
- 该研究强调了V-doped MoOX在推进高效光伏技术方面的潜力.
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