调节从工业废物中获得的硬碳的结构,以提高储存性能
Zhiyong Yang1, Pandeng Zhao2, Xiangxi He3
1School of Materials Science and Engineering, Xiangtan University, Xiangtan 411105, China; College of Chemistry and Materials Engineering, Wenzhou University, Wenzhou, Zhejiang 325035, China; Wenzhou Key Laboratory of Sodium-Ion Batteries, Wenzhou University Technology Innovation Institute for Carbon Neutralization, Wenzhou, Zhejiang 325035, China.
通过高温碳化回收废物前体,可以为离子电池 (SIB) 制造高效的硬碳阳极. 基于以太的电解质增强了的储存,在SIB应用中显示出有前途的结果.
科学领域:
- 材料科学 材料科学 材料科学
- 电化学 电化学 电化学
- 可持续能源 可持续能源
背景情况:
- 由于成本和可用性,生物质衍生的硬碳是离子电池 (SIB) 的阳极材料.
- 高昂的生产成本源于低碳化产量和工业废物.
- 优化电解质对于提高储能能力至关重要.
研究的目的:
- 从废弃物前体中开发具有成本效益的硬碳阳极材料,使用高温碳化.
- 为了研究电解质类型对储存性能的影响.
- 为了评估在SIB袋和圆柱形电池中制造的硬碳阳极的性能.
主要方法:
- 废弃物前体的高温碳化产生硬碳材料.
- 在现场进行拉曼特征,以比较电解质效应.
- 离子电池电池的制造和电化学测试 (袋式和18650圆柱形).
主要成果:
- 回收的硬碳材料表现出增强的储存能力.
- 与以为基础的电解质相比,以为基础的电解质显示出更高的性能.
- 组装的电池实现了高可逆容量 (406 mAh用于袋式电池,674 mAh用于18650个电池).
结论:
- 简单的回收方法可以为SIBs生产高性能硬碳阳极.
- 基于以太的电解质对这些系统中的储存有好处.
- 开发的材料显示出商业SIB应用的巨大潜力,降低成本和提高性能.
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