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相关概念视频

Surface Tension of Fluid01:22

Surface Tension of Fluid

173
Surface tension is a fundamental property of fluids, occurring at the boundary between a liquid and a gas or between two immiscible liquids. This phenomenon arises from the cohesive forces between molecules at the fluid's surface, creating an effect similar to a stretched elastic membrane. Inside each fluid, molecules are equally attracted in all directions by neighboring molecules, but surface molecules experience a net inward force, resulting in surface tension.
Surface tension varies...
173
Surface Tension and Surface Energy01:16

Surface Tension and Surface Energy

1.3K
When a paint brush is immersed in water, the bristles wave freely inside the water. When it is taken out, the bristles stick together. The reason behind this effect is surface tension.
Consider a beaker filled with liquid. The bulk molecules in the liquid experience equal attractive forces on all sides with the surrounding molecules. However, the surface molecules experience a net attractive force downward due to the bulk molecules. The surface of the liquid behaves like a stretched membrane,...
1.3K
Phase Transitions: Melting and Freezing02:39

Phase Transitions: Melting and Freezing

12.2K
Heating a crystalline solid increases the average energy of its atoms, molecules, or ions, and the solid gets hotter. At some point, the added energy becomes large enough to partially overcome the forces holding the molecules or ions of the solid in their fixed positions, and the solid begins the process of transitioning to the liquid state or melting. At this point, the temperature of the solid stops rising, despite the continual input of heat, and it remains constant until all of the solid is...
12.2K
Contact Angle01:13

Contact Angle

11.5K
When a solid is dipped inside a liquid, the liquid surface becomes curved near the contact. For some solid–liquid interfaces, the liquid is pulled up along the solid, while for others, the liquid surface is convex or depressed near the solid surface. This phenomenon can be explained using the concept of cohesive and adhesive forces.
The adhesive force is the molecular force between molecules of different materials, that is, between the molecules of the solid and the liquid. The cohesive...
11.5K
Enthalpy of Solution02:39

Enthalpy of Solution

24.4K
There are two criteria that favor, but do not guarantee, the spontaneous formation of a solution:
24.4K
Membrane Fluidity01:23

Membrane Fluidity

149.7K
Cell membranes are composed of phospholipids, proteins, and carbohydrates loosely attached to one another through chemical interactions. Molecules are generally able to move about in the plane of the membrane, giving the membrane its flexible nature called fluidity. Two other features of the membrane contribute to membrane fluidity: the chemical structure of the phospholipids and the presence of cholesterol in the membrane.
149.7K

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Analyzing Melts and Fluids from Ab Initio Molecular Dynamics Simulations with the UMD Package
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来自计算机模拟的固体-液体界面自由能量:挑战和最近的进展.

Nicodemo Di Pasquale1, Jesús Algaba2, Pablo Montero de Hijes3

  • 1Department of Industrial Chemistry "T. Montanari", Università di Bologna, via Gobetti 85, 40129 Bologna, Italy.

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概括

计算固体-液体界面自由能量对于理解材料特性至关重要. 本综述概述了包括直接和间接方法在内的数值方法,以应对这个复杂领域的模拟挑战.

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科学领域:

  • 热力学是一种热力学.
  • 材料科学 材料科学 材料科学
  • 计算物理 计算物理

背景情况:

  • 液体系统的界面特性研究了200年.
  • 固体-液体界面热力学由于固体结构而复杂.
  • 准确的界面自由能量计算是预测界面行为的关键.

研究的目的:

  • 为固体-液体界面自由能量计算提供数值方法的概述.
  • 将现有方法分为直接和间接类别.
  • 讨论诸如核化理论和曲面接口等相关主题.

主要方法:

  • 对数值模拟技术的审查.
  • 将方法分为直接方法和间接方法.
  • 讨论固体液体系统所面临的挑战 (例如,格子方向性).

主要成果:

  • 固体-液体界面自由能量计算具有挑战性,但至关重要.
  • 直接方法明确计算自由能量.
  • 间接方法从模拟分析中获得自由能量.

结论:

  • 数字方法对于理解固体-液体接口至关重要.
  • 直接和间接方法为计算界面自由能量提供了不同的途径.
  • 进一步的研究正在核化理论和曲的固体-液体接口中进行.