没有稀土的磁热材料Fe82Hf6Zr7B4Cu1用于高温应用
Anjana Vinod1, Arvindha Babu Diraviam2, Manivel Raja Muthuvel2
1School of Advanced Sciences, Vellore Institute of Technology Vellore 632014 Tamil Nadu India.
RSC advances
|May 12, 2025
概括
这项研究探讨了一种用于磁热冷却的新型Fe-Hf-Zr-B-Cu带. 由于其显著的磁变化,该材料对高温应用具有前景.
科学领域:
- 材料科学 材料科学 材料科学
- 凝聚物质物理学 凝聚物质物理学
- 热力学是一种热力学.
背景情况:
- 磁热效应 (MCE) 对磁性冷却技术至关重要.
- 对于MCE应用,越来越多地寻求没有稀土 (RE) 的材料.
- 对于先进的冷却系统,需要使用高温MCE材料.
研究的目的:
- 系统地描述新型Fe82Hf6Zr7B4Cu1带的结构,磁性和磁热性质.
- 评估这些带在高温磁热应用中的潜力.
主要方法:
- 用于结构分析的X射线衍射 (XRD).
- 测量磁性特性以确定库里过渡温度.
- 测量磁热性质,以评估变化,冷却功率和制冷能力.
主要成果:
- XRD证实了哈夫被纳入Fe-Zr-B-Cu矩阵中的情况.
- 观察到的基里过渡温度为678K.
- 在2.0 T时实现了0.448 J kg-1 K-1 的磁变化.
- 相对冷却功率和制冷容量分别为11.87 J kg-1和14.0 J kg-1.
结论:
- 铁82Hf6Zr7B4Cu1带显示出有希望的磁热性质.
- 这种材料是高温磁热热制冷设备的强有力的候选者.
相关概念视频
Ferromagnetism
2.4K
Materials like iron, nickel, and cobalt consist of magnetic domains, within which the magnetic dipoles are arranged parallel to each other. The magnetic dipoles are rigidly aligned in the same direction within a domain by quantum mechanical coupling among the atoms. This coupling is so strong that even thermal agitation at room temperature cannot break it. The result is that each domain has a net dipole moment. However, some materials have weaker coupling, and are ferromagnetic at lower...
2.4K
Paramagnetism
2.5K
Paramagnets are materials with unpaired electrons that possess a finite magnetic moment. In the absence of a magnetic field, these moments are randomly oriented, and thus the net moment is zero. Under an external field, a torque acting on the moments tends to align them along the field's direction. However, the random thermal motion of electrons produces a torque opposite to the external field and tries to disorient the moments. These two competing effects align only a few moments along the...
2.5K
Diamagnetism
2.4K
Materials consisting of paired electrons have zero net magnetic moments. However, when these materials are placed under an external magnetic field, the moments opposite to the field are induced. Such materials are called diamagnets. Diamagnetism is the response of the diamagnets when placed in an external magnetic field.
Diamagnetism was discovered by Anton Brugmans in 1778 when he observed that bismuth gets repelled by magnetic fields, thus theorizing that diamagnets get repelled by magnets....
Diamagnetism was discovered by Anton Brugmans in 1778 when he observed that bismuth gets repelled by magnetic fields, thus theorizing that diamagnets get repelled by magnets....
2.4K
Potential Due to a Magnetized Object
248
Magnetic dipoles in magnetic materials are aligned when placed under an external magnetic field. For paramagnets and ferromagnets, dipole alignment occurs in the direction of the magnetic field. However, the dipoles align opposite to the field in the case of diamagnets. This state of magnetic polarization due to the external field is called magnetization. Magnetization is defined as the dipole moment per unit volume. It plays a similar role to polarization in electrostatics.
The vector...
The vector...
248
Magnetism
6.1K
Magnets are commonly found in everyday objects, such as toys, hangers, elevators, doorbells, and computer devices. Experimentation on these magnets shows that all magnets have two poles: one is labeled north (N) and the other south (S). Magnetic poles repel if they are alike and attract if unlike. Moreover, both poles of a magnet attract unmagnetized pieces of iron.
An individual magnetic pole cannot be isolated. No matter how small, every piece of a magnet contains a north pole and a south...
An individual magnetic pole cannot be isolated. No matter how small, every piece of a magnet contains a north pole and a south...
6.1K
Colors and Magnetism
11.4K
Color in Coordination Complexes
When atoms or molecules absorb light at the proper frequency, their electrons are excited to higher-energy orbitals. For many main group atoms and molecules, the absorbed photons are in the ultraviolet range of the electromagnetic spectrum, which cannot be detected by the human eye. For coordination compounds, the energy difference between the d orbitals often allows photons in the visible range to be absorbed and emitted, which is seen as colors by the human...
When atoms or molecules absorb light at the proper frequency, their electrons are excited to higher-energy orbitals. For many main group atoms and molecules, the absorbed photons are in the ultraviolet range of the electromagnetic spectrum, which cannot be detected by the human eye. For coordination compounds, the energy difference between the d orbitals often allows photons in the visible range to be absorbed and emitted, which is seen as colors by the human...
11.4K


