孔隙结构和煤炭基本特性对煤炭高效气体吸附能力的影响
Zhengfeng Yu1,2, Jianping Bai1,2,3, Jindong Yang1,2
1National Key Laboratory of Coal and CBM Co-mining, Jincheng 048012, China.
ACS omega
|May 12, 2025
概括
煤床甲储量中的高效气体吸附取决于孔隙结构. 发达的毛孔和连接的网络增强了甲产量. 透法克塔尔维度 (D1) 是有效的脱吸能力的关键.
科学领域:
- 地质科学 地质科学
- 能源科学 能源科学
背景情况:
- 气体吸附能力对于优化煤床甲储量中的甲回收至关重要.
- 了解孔隙结构和气体脱吸之间的关系对于高效的资源提取至关重要.
研究的目的:
- 调查来自水盆地的煤炭样本的气体脱吸能力和孔状结构.
- 提出一种高效脱吸能力的定义,并评估其与孔隙特征和碎形尺寸的相关性.
- 探索煤炭特性对高效消耗能力的影响.
主要方法:
- 进行了同热吸附实验.
- 进行了注射毛细血管压力测试.
- 使用了碎形维度 (透D1和扩散D2) 的分析.
主要成果:
- 煤炭样本显示出发达的微孔和过渡孔.
- 较大的孔径和连接良好的孔径网络对高效的甲脱吸和运输产生积极影响.
- 透法克塔尔维度 (D1) 与有效的脱吸能力有正相关性,而扩散法克塔尔维度 (D2) 的影响较小.
- 煤等级,玻璃矿石和内矿石含量影响了脱吸能力,尽管关系需要进一步澄清.
结论:
- 孔隙结构,特别是孔隙体积和连接性,显著影响煤床甲储库中高效的甲脱氧和产量.
- 透法克塔尔维度 (D1) 作为一个可靠的指标来评估高效的脱吸能力.
- 需要进一步的研究来澄清煤炭内在性质对溶解效率的影响.
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