核和超冷减缓脂肪酒精相变材料乳液中的核和超冷减缓用于热传输和储存
Moritz Kick1,2, Sebastian Gamisch1, Alexander Wittemann2
1Fraunhofer Institute for Solar Energy Systems ISE, Heidenhofstr. 2, 79110 Freiburg, Germany.
ACS omega
|May 12, 2025
概括
这项研究发现,长链聚合物减少了脂肪酒精乳液中的超冷,改善了它们在热能存储的相变材料 (PCM) 中的使用. 然而,种子失活需要进一步的研究,以获得持续的性能.
科学领域:
- 材料科学 材料科学 材料科学
- 化学工程是化学工程的重要组成部分.
- 热力学是一种热力学.
背景情况:
- 有机相变泥 (PCS) 遭受超冷却,降低热储能中的能源效率.
- 与基相比,对脂肪酒精乳液中超冷机制的研究是有限的.
研究的目的:
- 研究核化剂对降低1-多可萨 (脂肪酒精) 油入水乳液中超冷的作用.
- 确定兼容的核化促进剂,以提高相变材料的性能.
主要方法:
- 通过使用旋转器-静止器乳化,制造出具有平板皮层颗粒大小分布的油在水乳液.
- 选了各种材料组合的核化促进剂.
- 利用热分析和晶体结构分析来评估超冷却缓解.
主要成果:
- 长链聚合物有效地减少了1-多可萨乳液中的超冷,特别是在旋转器相位过渡期间.
- 超冷却被平均减少了9K.
- 在热循环中观察到种子失活,导致超冷的逐渐增加.
结论:
- 乳液组件之间的高度结构相似性是最小化PCS中超冷却的关键.
- 颗粒大小,表面活性剂和核化剂影响核化速率和障碍.
- 这些发现增强了脂肪酒精乳液在热能存储应用中的潜力.
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