在干燥过程中,NaCl-NaNO3-H2O在有孔的介质中结晶
Leo Pel1, Sebastiaan Godts2, Amelie Stahlbuhk3
1Department of Applied Physics, Transport in Permeable Media, Eindhoven University of Technology, P.O. Box 513, 5600 MB Eindhoven, The Netherlands.
Crystal growth & design
|May 12, 2025
概括
在干燥过程中在多孔介质中盐混合物的结晶是由运输驱动的,而不仅仅是平衡. 超和效应意味着单独的相位图无法预测这些条件下的盐的行为.
科学领域:
- 地质化学 地质化学
- 物理化学 物理化学
- 环境科学 环境科学
背景情况:
- 盐混合物在自然和工业多孔介质中很常见.
- 了解干燥过程中的盐结晶对于预测材料行为和环境命运至关重要.
研究的目的:
- 在干燥过程中在多孔介质中研究三元盐混合物 (NaCl-NaNO3-H2O) 的结晶.
- 为了确定平衡相位图是否足以描述在干燥条件下的盐结晶.
主要方法:
- 使用专门的4.7 T核磁共振装置在现场测量NaCl和NaNO3度.
- 在强制干燥实验中跟踪盐的比例,具有主导离子向导 (Peclet数> 5).
主要成果:
- 仅仅以平衡相图不足以描述干燥过程中在多孔介质中的盐结晶.
- 结晶是运输驱动的,受到超和和向导的影响.
- 盐的比例 (Na+,Cl-,NO3-) 保持不变,导致NaCl和NaNO3的形成.
结论:
- 蒸发速度,超和和溶液运输可以导致超越相位图预测的和度.
- 这种现象对于在多孔介质中评估混合盐系统至关重要.
- 为了准确的预测,必须与运输现象一起考虑相位图.
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