在实验室规模燃烧中,从每天200t/d热解示范工厂获得的MSW热解炭中,的演化特征
Zhaotianyi Zhang1, Ao Zhou1, Guan Wang1
1MOE Key Laboratory of Thermo-Fluid Science and Engineering, Xi'an Jiaotong University, Xi'an, Shaanxi 710049, PR China.
Waste management (New York, N.Y.)
|May 13, 2025
概括
这项研究检查了城市固体废物 (MSW) 中的. 燃烧释放有机作为HCl,而无机形成Cl2或化物,影响煤炭的再利用.
科学领域:
- 环境化学环境化学
- 材料科学 材料科学 材料科学
- 废物管理 废物管理
背景情况:
- 热解是城市固体废物 (MSW) 处理的关键方法.
- 在MSW中的会产生有害化合物,如二氧化,Cl2和HCl.
- 了解MSW热解炭中的的行为对于安全的再利用至关重要.
研究的目的:
- 为了研究MSW热解燃烧过程中的演变.
- 分析在图表中的物种化和分布.
- 为了确定煤炭特性对燃烧过程中释放的影响.
主要方法:
- 来自200t/d示范项目的MSW热解炭的分析.
- 用于物种的X射线光 (XRF) 和X射线光电子光谱 (XPS).
- 热重力测量-里埃变换红外光谱-质谱 (TG-FTIR-MS) 用于燃烧分析.
主要成果:
- 火解炭中含有9.28%的 (12.83%的有机-Cl,87.17%的无机-Cl).
- 燃烧释放有机Cl作为HCl;无机Cl转化为Cl2或金属化物,形成HCl.
- 有机Cl解离发生在220-320°C (HCl) 和400-550°C (Cl2) 之间.
- 煤炭的微孔结构促进了气的扩散.
结论:
- 燃烧MSW热解炭将转化为气态HCl和Cl2.
- 增加热解温度和时间会降低炭含量.
- 这些发现为MSW热解炭的安全和有效的再利用提供了洞察力.
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