在基于Ti的齐格勒-纳塔催化剂中计数活性位点的染色体灭标记
Antonio Vittoria1, Giuseppe Antinucci1, Roberta Cipullo1
1Department of Chemical Sciences, Federico II University of Naples, Via Cinthia, 80126 Napoli, Italy.
Polymers
|May 14, 2025
概括
染色体灭标记 (CQL) 成功量化了聚合物的齐格勒-纳塔催化剂中的活性位. 这种方法的结果与灭流量 (QF) 方法相似,揭示了低活性位点分数.
科学领域:
- 催化剂是一种催化剂.
- 聚合物化学 聚合物化学
- 材料科学 材料科学 材料科学
背景情况:
- 奥莱芬聚合依赖于过渡金属催化剂.
- 量化活性位点对于催化剂效率至关重要.
- 染色体火标记 (CQL) 是分子催化剂的一种成熟方法.
研究的目的:
- 首次将CQL应用于基于Ti的异质齐格勒-纳塔催化剂.
- 为了确定工业烯聚合物中的活性金属位点 (x*) 分数.
- 将CQL结果与现有方法比较,例如灭流量 (QF).
主要方法:
- 染色体灭标记 (CQL) 技术的应用.
- 使用1-hexene作为聚合物的单体.
- 与灭流量 (QF) 数据进行烯聚合的比较.
主要成果:
- 在异质的齐格勒-纳塔催化剂中,CQL成功量化了活性位.
- 确定的活性部位分数 (x*) 为1-烯聚合的0.49±0.09%.
- 这个值与以前用于烯聚合的QF测量非常一致.
结论:
- 对于基于Ti的异质齐格勒-纳塔催化剂,CQL是有效的.
- 低活性部位分数表明暂时的,转移稳定的表面Ti添加物是活性物种.
- 这一发现支持最近关于催化物种的文献建议.
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