阻燃纤维素研究的进展及其在聚合物中的应用:一篇综述
Quan Yuan1,2,3, Shaodong Wang1,2,3, Liping He1,2
1State Key Laboratory of Advanced Design and Manufacturing Technology for Vehicle, Hunan University, Changsha 410082, China.
Polymers
|May 14, 2025
概括
阻燃纤维素通过克服自然可燃性,为聚合物提供了更高的安全性. 研究审查了各种修改方法和应用,突出了先进复合材料的潜力.
科学领域:
- 材料科学 材料科学 材料科学
- 聚合物化学 聚合物化学
- 绿色化学 绿色化学
背景情况:
- 纤维素是一种可再生的聚合物,具有理想的特性,但患有易燃性.
- 可燃性限制了纤维素在汽车和电子等关键行业的应用.
- 开发阻燃纤维素对于扩大其使用至关重要.
研究的目的:
- 审查阻燃纤维素修饰的最新进展.
- 讨论各种制造方法及其有效性.
- 探索在聚合物复合材料中修改纤维素的应用.
主要方法:
- 修改策略的审查,包括,,,硫,无机和协同方法.
- 使用热重量计,热量计,限制氧指数和UL94垂直燃烧等技术评估火焰阻燃性.
- 复合材料中阻燃纤维素应用的分析.
主要成果:
- 多面性修改策略显著改善了纤维素的阻燃性能.
- 阻燃纤维素在复合材料中显示出广泛的应用前景.
- 各种修改方法有效地提高了消防安全特性.
结论:
- 阻燃纤维素对聚合物应用具有非凡的潜力.
- 未来的研究应该专注于接口兼容性,环境影响和流程优化.
- 开发高效,低毒性和工业规模的阻燃纤维素是非常重要的.
相关概念视频
Polymers
32.8K
The word polymer is derived from the Greek words “poly” which means “many” and “mer” which means “parts”. Polymers are long chains of molecules composed of repeating units of smaller molecules, known as monomers. They either occur naturally, such as DNA and proteins, or can be constructed synthetically, like plastics. They have varied structural characteristics, such as linear chains, branched chains, or complex networks, that contribute to the...
32.8K
Polymer Classification: Architecture
2.9K
Polymers are classified as linear or branched on the basis of their chain architecture. The polymer chains in linear polymers have a long chain-like structure with minimal to no branching at all. Even if a polymer features large substituent groups on the monomer, which appear as branches to the skeleton, it is not considered a branched polymer. A branched polymer contains secondary polymer chains that arise from the main polymer chain. The branching occurs when the polymer growth shifts from...
2.9K
Molecular Weight of Step-Growth Polymers
2.1K
Step growth polymerization involves bi or multifunctional monomers. Bifunctional monomers react to form linear step growth polymers, whereas multifunctional monomers react to form non-linear or branched polymers.
As the step-growth polymerization involves step-wise condensation of monomers, the molecular weight also builds up eventually. Consequently, high molecular weight polymers are obtained at the late stages of the polymerization, where 99% of monomers have been consumed.
The extent of the...
As the step-growth polymerization involves step-wise condensation of monomers, the molecular weight also builds up eventually. Consequently, high molecular weight polymers are obtained at the late stages of the polymerization, where 99% of monomers have been consumed.
The extent of the...
2.1K
Types of Step-Growth Polymers: Polyesters
1.7K
The introduction of polyesters has brought major development to the textile industry. The wrinkle-free behavior of polyester blends has eliminated the need for starching and ironing clothes.
Polyesters are commonly prepared from terephthalic acid and ethylene glycol; the crude product is known as poly(ethylene terephthalate) or PET. However, polyesters are synthesized industrially by transesterification of dimethyl terephthalate with ethylene glycol at 150 °C. The two reactants and the...
Polyesters are commonly prepared from terephthalic acid and ethylene glycol; the crude product is known as poly(ethylene terephthalate) or PET. However, polyesters are synthesized industrially by transesterification of dimethyl terephthalate with ethylene glycol at 150 °C. The two reactants and the...
1.7K
Cellulose and Pectic Polysaccharides
3.6K
Every plant cell has a cell wall that protects the cell, provides structural support, and gives the cell shape. Cellulose, the main structural component of the plant cell wall, makes up over 30% of plant matter. It is the most abundant organic compound on earth. Cellulose is an unbranched polysaccharide composed of linear chains of glucose molecules linked by β (1→4) glycosidic bonds.
As a cell matures, its cell wall specializes according to its type. For example, the...
As a cell matures, its cell wall specializes according to its type. For example, the...
3.6K
Bioplastics
70
Bioplastics derived from microbial processes present a sustainable alternative to conventional petroleum-based plastics. Among these, polyhydroxyalkanoates (PHAs), particularly polyhydroxybutyrates (PHBs), have emerged as prominent candidates due to their biodegradability and biocompatibility. These polymers are synthesized by a variety of bacteria, such as Cupriavidus necator and Pseudomonas putida, which naturally accumulate PHAs as intracellular carbon and energy reserves, especially under...
70


