从回收聚烯和低成本泡剂生产的泡的分析:使用孔径大小,分布,剪切效应和热特性进行基准测试
Krishnamurthy Prasad1, Fareed Tamaddoni Jahromi1, Shammi Sultana Nisha1
1School of Engineering, Swinburne University of Technology, Hawthorn, VIC 3122, Australia.
Polymers
|May 14, 2025
概括
这项研究探讨了环保泡剂,用于从原始和回收材料制造聚乙烯泡. 回收的LLDPE泡由于其混合相性而表现出更多的孔积聚.
科学领域:
- 材料科学 材料科学 材料科学
- 聚合物化学 聚合物化学
背景情况:
- 聚乙烯泡被广泛使用,但通常是从处女聚合物中衍生出来的.
- 使用回收材料开发可持续替代品对于减少环境影响至关重要.
研究的目的:
- 调查从原始和回收的线性低密度聚乙烯 (LLDPE) 和低密度聚乙烯 (LDPE) 制造泡样品.
- 为了评估低成本泡剂的性能:酸 (CA) 和碳酸 (NaB).
- 为了比较制造的聚乙烯泡与聚氨泡的性能.
主要方法:
- 使用原始/回收的LLDPE和LDPE与CA和NaB泡剂制造泡样本.
- 使用固态粉碎和高剪切内部混合技术.
- 分析的关键性质:密度,孔径,形状,分布,结晶性和多孔性.
主要成果:
- 处女LLDPE和回收LDPE泡显示出狭窄的孔径分布和减少的结晶性.
- 回收的LLDPE泡呈现出较高的孔积聚率,这归因于它们的混合相性.
- 与酸 (CA) 泡相比,二碳酸 (NaB) 泡的密度较低.
结论:
- 酸和碳酸是可行的低成本聚乙烯泡剂.
- 回收LLDPE的混合相性影响泡形态不同于单相初始LLDPE和回收LDPE.
- 泡剂的分解行为会影响最终的泡密度和结构.
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