屏蔽CO2-Philic站点通过原子层沉积修剪共价有机框架孔
Zhiwen Chen1,2, Jipeng Xu3, Ming Zhang1,2
1State Key Laboratory of Chemical Engineering, College of Chemical and Biological Engineering, Zhejiang University, 866 Yuhangtang Rd, Hangzhou, 310058, China.
Small (Weinheim an der Bergstrasse, Germany)
|May 14, 2025
概括
原子层沉积 (ALD) 通过屏蔽吸附点来改变多孔共价有机框架 (COF). 这种孔隙工程增强了薄吸附气体的膜分离性能,例如气超过二氧化碳.
科学领域:
- 材料科学 材料科学 材料科学
- 化学工程是化学工程的重要组成部分.
- 纳米技术纳米技术
背景情况:
- 多孔框架材料由于强烈的吸附点,经常表现出反向的吸附选择性,阻碍了弱吸附气体的膜分离.
- 对于共价有机框架 (COFs) 的现有后合成修改方法主要集中在孔隙缩小上,忽视了保护高度吸附性区域的策略.
研究的目的:
- 开发一种有效的策略来屏蔽COF孔内的高度吸附性位点.
- 通过提高弱吸附物种的选择性来增强扩散驱动的膜分离.
主要方法:
- 使用原子层沉积 (ALD) 的无溶剂孔隙修饰策略被采用.
- 控制氧化物 (ZnO) 沉积到COF毛孔中,以微调毛孔尺寸和屏蔽吸附部位.
主要成果:
- 实现了ZnO在COF毛孔中的均沉积,从而能够精确控制毛孔尺寸.
- Zn─O 分子通过与CO2-philic胺基群相互作用,使CO2溶解度降低了72.4%.
- 由于增强的扩散和吸收选择性,观察到H2/CO2的永久选择性得到了330%的改善.
结论:
- 通过屏蔽吸附部位,ALD提供了一种有效的孔工程方法.
- 这种孔隙修饰策略显著提高了像H2/CO2这样的气体对的膜分离性能.
相关概念视频
Electrical Conductivity
1.1K
In perfect conductors, the electric field inside is always zero due to the abundance of free electrons, which nullify any field by flowing. As a result, any residual charge resides on the surface.
In a practical conductor, an applied electric field may be sustained, causing a flow of electrons, which produce a current. The differential form of the current, the current density, is related to the electric field.
More generally, it is related to the force per unit charge, which involves the...
In a practical conductor, an applied electric field may be sustained, causing a flow of electrons, which produce a current. The differential form of the current, the current density, is related to the electric field.
More generally, it is related to the force per unit charge, which involves the...
1.1K
Diamagnetic Shielding of Nuclei: Local Diamagnetic Current
790
An applied magnetic field causes the electrons present in the molecule to circulate, setting up a local diamagnetic current within the molecule. The local diamagnetic current arising from circulating sigma-bonding electrons induces a magnetic field, Blocal that opposes the applied magnetic field, B0. The effective magnetic field experienced by these nuclei is given by the difference between the applied and local magnetic fields in a phenomenon called local diamagnetic shielding. Essentially,...
790
Resistivity
3.3K
When a voltage is applied to a conductor, an electrical field is generated, and charges in the conductor feel the force due to the electrical field. The current density that results depends on the electrical field and the properties of the material. In some materials, including metals at a given temperature, the current density is approximately proportional to the electrical field. In these cases, the current density can be modeled as:
3.3K
Equipotential Surfaces and Conductors
3.3K
For a conductor in which all charges are at rest, the conductor's surface is equipotential. The electric field is always perpendicular to equipotential surfaces. Therefore, in a conductor with static charges, the electric field just outside the conductor is always perpendicular to the conductor's surface. Any tangential component of the electric field will cause charges to move inside the conductor, which will violate the electrostatic nature of the system. In an electrostatic...
3.3K
Resistance and Conductance
67
A conductor's DC resistance at a given temperature is influenced by its resistivity, length, and cross-sectional area. Resistivity is an inherent property of the conductor material, with annealed copper serving as the international standard for measurement. For instance, the resistivity of hard-drawn aluminum at 20 degrees Celsius is 61% of the standard conductivity of annealed copper.
Various factors impact the resistance of a conductor. Spiraling in stranded conductors increases their...
Various factors impact the resistance of a conductor. Spiraling in stranded conductors increases their...
67
Theory of Metallic Conduction
1.3K
The conduction of free electrons inside a conductor is best described by quantum mechanics. However, a classical model makes predictions close to the results of quantum mechanics. It is called the theory of metallic conduction.
In this theory, Newton's second law of motion is used to determine the acceleration of an electron in the presence of an applied electric field. Then, its velocity is expressed via this acceleration.
An electron moves through the crystal, containing positive ions,...
In this theory, Newton's second law of motion is used to determine the acceleration of an electron in the presence of an applied electric field. Then, its velocity is expressed via this acceleration.
An electron moves through the crystal, containing positive ions,...
1.3K


