铁弹性框架中的巨大负面区域可压缩性
Muzi Chen1,2, Hanna L B Boström3,4, Dominik Daisenberger5
1Department of Materials, Imperial College London, Royal School of Mines, Exhibition Road, London SW7 2AZ, U.K.
铜I) 三甲 (Cu) tcm) 显示出有史以来最强的负面面积压缩性 (NAC). 这种灵活的框架材料显示出先进的压力传感器和减震装置的潜力.
科学领域:
- 材料科学
- 晶体学
- 材料的机械学
背景情况:
- 铜甲 (Cu) 是一种柔性框架材料.
- 负区域可压缩性 (NAC) 是一种罕见的现象,在传感器和执行器中具有潜在的应用.
研究的目的:
- 研究压力诱导的阶段转换和Cu (tcm) 的压缩性.
- 阐明观察到的负面面积可压缩性 (NAC) 和负线性可压缩性 (NLC) 的机制.
主要方法:
- 在水静压下单晶X射线衍射.
- 在不同压力范围内分析结构变化和压缩性.
主要成果:
- (tcm) 经历两种相位过渡:在0.12 (tcm) GPa时由四边形变为正边形,在0.93 (tcm) GPa时由正边形变为单边形.
- 由于框架链运动,形阶段表现出强烈的NAC (-108~14) TPa-1.
- 单临床阶段在a轴上显示轻微的NLC和a-c平面上的零区域压缩性,归因于受湿层波动.
结论:
- Cu ((tcm) 显示与其结构阶段转换相关的不同的NAC和NLC行为.
- 了解这些机制可以在灵活的框架材料中深入了解NAC现象.
- 的独特可压缩性特性表明它有可能用于新型设备.
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