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Updated: May 16, 2025

Synthesis of Metal Nanoparticles Supported on Carbon Nanotube with Doped Co and N Atoms and its Catalytic Applications in Hydrogen Production
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基于正方形平面四核集群的高对称协调金属有机聚合物,用于高效的电化学酸盐降解为氨

Miao Wang1, Ya-Ru Meng2, Wenjie Xu3

  • 1State Key Laboratory of Coordination Chemistry, MOE Key Laboratory of Mesoscopic Chemistry, MOE Key Laboratory of High Performance Polymer Materials and Technology, Jiangsu Key Laboratory of Advanced Organic Materials, Suzhou Key Laboratory of Green Intelligent Manufacturing of New Energy Materials and Devices, Tianchang New Materials and Energy Technology Research Center, Institute of Green Chemistry and Engineering, School of Chemistry and Chemical Engineering, Nanjing University, Nanjing, Jiangsu 210023, P. R. China.

Journal of the American Chemical Society
|May 14, 2025
PubMed
概括

金属有机聚合物 (MOP) 能够有效地将电化学酸盐转化为氨. 基于的MOP (Co-TATB) 达到约98%的氨选择性,为催化剂设计提供了洞察力.

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Coordination Number and Geometry

For transition metal complexes, the coordination number determines the geometry around the central metal ion. Table 1 compares coordination numbers to molecular geometry. The most common structures of the complexes in coordination compounds are octahedral, tetrahedral, and square planar.
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Isomerism in Complexes
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