在实用的离子电池中重新审视化环素的界面增强效应
Yixiao Zhang1, Zichen Wu1,2, Yong Wang1,2
1School of Chemistry and Chemical Engineering, in-situ Center for Physical Sciences, Shanghai Electrochemical Energy Device Research Center (SEED), Shanghai Jiao Tong University, Shanghai 200240, China.
ACS applied materials & interfaces
|May 16, 2025
概括
乙氧 (五) 循环三酸 (PFPN) 通过在电极上形成保护层来增强离子电池. 这提高了低温性能和循环稳定性,这对于先进的能量存储至关重要.
科学领域:
- 材料科学 材料科学 材料科学
- 电化学 电化学 电化学
- 储能 储能 储能 储能 储能 储能
背景情况:
- 离子电池 (SIB) 具有成本效益和良好的低温性能.
- 挑战包括缓慢的动力学和碳阳极的涂层.
研究的目的:
- 作为SIBs的电解质添加剂,研究乙氧 (五) 环三 (PFPN).
- 为了提高Na0.98Ni0.5Fe0.2Mn0.3O2硬碳袋细胞的性能和稳定性.
主要方法:
- 将PFPN,一种阻燃剂添加剂,加入到实用的SIB袋式电池的电解质中.
- 对固体电解质介相 (SEI) 形成及其组成 (和丰富) 的分析.
主要成果:
- 在电极上,PFPN分解成一个统一的SEI层.
- 优化的SEI增强了接口动力学,并抑制了涂层.
- 囊细胞表现出极好的循环稳定性:在0°C的450个循环后85%的保留率,在30°C的600个循环后84%.
结论:
- PFPN是一种有前途的电解质添加剂,用于高性能,长寿命的SIB.
- PFPN显著提高了SIB的性能,特别是在低温下.
- 这项研究为储能系统的先进电解质设计提供了洞察力.
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