来自生物质的功能添加剂,用于高效和稳定的合物基矿太阳能电池,内置固定装置
Jing Li1, Xiang Qiao2, Bingchen He3
1Department of Chemistry, School of Physical and Chemical Sciences (SPCS), Queen Mary University of London London E1 4NS UK yao.lu@qmul.ac.uk.
概括
一种新的生物质衍生聚合物 - - 甲基酸盐 (TBA-Alg) 增强了矿太阳能电池 (PSC) 的稳定性,并防止了泄漏. 这项创新解决了合物化PSC商业化的关键挑战.
科学领域:
- 材料科学 材料科学 材料科学
- 可再生能源可再生能源是可再生能源.
- 环境科学 环境科学
背景情况:
- 酸矿太阳能电池 (PSC) 显示出高功率转换效率 (PCE),但存在稳定性问题和污染风险.
- 在PSC中不协调的离子会造成缺陷,降低设备的稳定性并造成环境危害.
研究的目的:
- 制定一种提高PSC稳定性和防止污染的战略.
- 通过缺陷被动化和离子管理,提高化物PSC的商业可行性.
主要方法:
- 一种生物质衍生的四甲基亚酸 (TBA-Alg) 聚合物的合成.
- 用TBA-Alg对倒置的p-i-n PSC进行修改,以在矿表面和粒度边界上形成保护网络.
- 评估PSC性能,储存和照明下的稳定性,以及在水中浸泡时的离子泄漏.
主要成果:
- 经过TBA-Alg修改的PSC实现了25.01%的PCE.
- 设备在储存2000小时后保持了95.5%的初始性能,在持续1050小时以60%的RH照明后保持了80%的效率.
- 即使在浸水下,TBA-Alg网络也抑制了83%的泄漏,证明了有效的离子管理.
结论:
- TBA-Alg有效地使缺陷无活性,并管理离子,显著提高PSC的稳定性和耐湿性.
- 这种方法同时提高PCE和稳定性,同时减轻污染,为PSC的商业化铺平了道路.
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