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Monovalent Cation Doping of CH3NH3PbI3 for Efficient Perovskite Solar Cells
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通过有机甲基化物矿的绑定有机离子抑制相变和高压无形化

Jiayi Li1, Jan Hofmann2, Robert M Stolz1

  • 1Department of Chemistry, Stanford University, Stanford, California 94305, United States.

Journal of the American Chemical Society
|May 16, 2025
PubMed
概括

有机基化物矿 (RCh-矿) 具有显著的结构稳定性,在不同温度和压力下没有相变. 这种增强的相位完整性归因于有机的共价连接,防止对光电子应用至关重要的结构变化.

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Properties of Organometallic Compounds

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All meta-directing substituents are deactivating groups. These substituents withdraw electrons from the aromatic ring, making the ring less reactive toward electrophilic substitution. For example, the nitration of nitrobenzene is 100,000 times slower than that of benzene because of the deactivating effect of the nitro group. The first step in an electrophilic aromatic substitution is the addition of an electrophile to form a resonance-stabilized carbocation. The energy diagrams for...
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