在电子吸收载体上通过复合活性站点在生产中共同实施优化Volmer和Heyrovsky反应
Li-Dong Wang1, Zi-Wei Lu1, Yu-Mei He1
1Key Lab of Fluorine and Silicon for Energy Materials and Chemistry of Ministry of Education, College of Chemistry and Materials, Jiangxi Normal University, Nanchang, 330022, P. R. China.
Advanced materials (Deerfield Beach, Fla.)
|May 19, 2025
概括
这项研究引入了一种新型的电催化剂,将单原子和纳米粒子结合在涂有化涂层的碳纳米管上,用于高效的性进化反应 (HER). 与商业/碳基准相比,新的催化剂显著提高了性能和耐用性.
科学领域:
- 材料科学 材料科学 材料科学
- 电化学 电化学 电化学
- 催化剂是一种催化剂.
背景情况:
- 在性介质中的演化反应 (HER) 面临着挑战,因为 (*H) 形成 (沃尔默反应) 和脱 (*H脱) (海洛夫斯基/塔菲尔反应) 之间的权衡.
- 优化HER不仅需要用于水解离的双功能活性位点,还需要对单个金属位点进行电子调制.
研究的目的:
- 通过协同结合 (Pt) 单个原子和Pt纳米颗粒在蚀刻的化 (eBN) 涂层碳纳米管 (Pt-eBN@CNT) 上,开发一种高效的性HER电催化剂.
- 通过协同吸附和eBN载体的电子提取效应来研究Volmer和Heyrovsky步骤的促进.
主要方法:
- 一个复合电催化剂 (Pt-eBN@CNT) 的合成,其中包含Pt单原子和Pt纳米粒子,固定在EBN涂层的碳纳米管上.
- 在性介质中进行电化学表征,以评估 HER 的性能,包括超电位和转换频率 (TOF).
- 在膜电极组件 (MEA) 电解器中进行测试,以评估在高温电催化条件下的耐用性.
主要成果:
- 这种Pt-eBN@CNT催化剂在10 mA cm−2时实现了令人印象深刻的25.1 ± 1.7 mV的超电位,在0.15 V和RHE时达到17.1 ± 1.3 s−1的TOF,Pt负载极低 (6 μgPt cm−2).
- 在相同的条件下,性能显著超过商业Pt/C基准,无论是在低和高催化剂负载下.
- 使用 Pt-eBN@CNT 的 MEA 电解器表现出极高的耐用性,其电荷转移量为 2.0 × 106 C·cm−2 在 1.0 A·cm−2 时,超过了基于 Pt 的最先进的电催化剂.
结论:
- 在eBN@CNT上Pt单原子和纳米颗粒的组合有效地促进了性HER中的Volmer和Heyrovsky步骤.
- 提取电子的eBN载体在优化催化动力学方面发挥着至关重要的作用.
- 这项工作突出了协同活性场合组合和载体效应对于推进像HER这样的多步电催化反应的重要性.
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