在酸盐玻璃中,内部摩擦和能量消耗在断裂过程中发生
Tina Waurischk1, Joachim Deubener2, Ralf Müller1,2
1Federal Institute for Materials Research and Testing (BAM), Richard-Willstätter-Straße 11, 12489 Berlin, Germany.
The Journal of chemical physics
|May 19, 2025
概括
通过动态机械热分析测量玻璃的内部摩擦与裂生长阻力相关. 这表明,来自Tg下放松现象的能量消耗影响了各种玻璃类型的断裂行为.
科学领域:
- 材料科学 材料科学 材料科学
- 固体力学 固体力学是什么
- 玻璃科学 玻璃科学
背景情况:
- 了解断裂期间的能量消散对于预测材料行为至关重要.
- 之前的研究已经确定了各种玻璃成分的惰性裂纹生长数据.
- 动态机械热分析 (DMTA) 是探测粘弹性特性的一个关键技术.
研究的目的:
- 研究不同玻璃类型的内部摩擦和断裂力学之间的关系.
- 探索Tg下放松现象在裂传播期间能量消散中的作用.
主要方法:
- 使用DMTA对13种不同的玻璃样本 (玻璃酸盐,酸盐,苏打,含) 测量内部摩擦 (损失触角, δ).
- 在0.250赫兹的频率范围内,在不对称地曲的玻璃梁上进行了实验.
- 温度从273K变化到玻璃过渡温度 (Tg).
主要成果:
- 在tan δ与T·Tg−1曲线下的面积和裂增长指数 (n) 之间发现了相关性.
- 裂增长指数 (n) 描述了裂速度 (v) 和应力强度 (KI) 之间的经验关系.
- 这表明,从亚Tg放松现象中能量消散的程度与裂生长阻力有关.
结论:
- 这项研究表明,粘弹性能量消散和玻璃的断裂性之间存在定量联系.
- 低Tg放松过程对控制玻璃断裂的能量消散机制作出了重大贡献.
- 内部摩擦测量可以作为玻璃等脆性材料中裂生长行为的预测器.
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