通过同质沉方法合成的C@Ni-NiO纳米颗粒的微结构和异常磁性特性
Zhen-Fei Yu1, Kun-Yu Su2, Duan-Qing Chen2
1Jiangsu Provincial Engineering Research Center of Low Dimensional Physics and New Energy, College of Science, Nanjing University of Posts and Telecommunications Nanjing 210023 China hxm@njupt.edu.cn.
RSC advances
|May 21, 2025
概括
同样分散的碳支持-氧化物 (C@Ni-NiO) 纳米粒子被合成. 研究了它们的磁性特性,揭示了微弱的交换偏差,受粒子大小和相位构成的影响.
科学领域:
- 材料科学 材料科学 材料科学
- 纳米技术纳米技术
- 磁力学 磁力学 是一种
背景情况:
- 碳支持的金属氧化物纳米粒子对于各种应用至关重要.
- 控制微观结构和相位构成是调整磁性质的关键.
研究的目的:
- 为了合成具有不同微观结构的C@Ni-NiO纳米粒子.
- 研究合成参数对微观结构和磁性特性的影响.
- 分析粒子大小,相量,接口效应和磁性行为之间的关系.
主要方法:
- 溶热反应和同质沉用于C@Ni(OH) 2合成.
- 气氛的化形成C@Ni-NiO纳米粒子.
- 使用XRD,XPS,SEM和TEM进行表征.
- 在室温和低温下通过SQUID进行磁性测量.
主要成果:
- 均分散的C@Ni-NiO纳米粒子,其NiO含量在8.2%至38.1%之间.
- Ni和NiO相的平均晶体大小分别为<80nm和<20nm.
- 室温的强制性在48oE和77oE之间.
- 观察到弱交换偏差 (≤30Oe),归因于低NiO异性质.
结论:
- 合成参数显著影响C@Ni-NiO纳米粒子的微观结构和磁性.
- 粒子大小,相位组成和接口效应是决定磁性行为的关键因素.
- 观察到的弱交换偏差表明了特定磁性应用的潜力.
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